Gel compositions

专利摘要:
PURPOSE: Provided is a gel composition which is a combination of a gelled ester composition, a gelled ether composition, a gelled alcohol composition, a gelled naturally-occurring fat and oil composition, or a combination thereof with a solvent. CONSTITUTION: The two-phase gel composition comprises a gelled ester composition comprising a mixture of an ester compound and a polymer compound selected from the group consisting of triblock copolymers, star polymers, radial polymers, multi-block copolymers, and a combination thereof, the gelled ester composition having a viscosity eta1; and a hydrophobic, non polar solvent, the solvent having a viscosity eta2, wherein the two-phase gel composition is substantially free of phosphate compounds and has a viscosity eta which is greater than or equal to eta1 and which is greater than or equal to eta2.
公开号:KR20020086829A
申请号:KR1020020022637
申请日:2002-04-25
公开日:2002-11-20
发明作者:부투크스텔루타지나
申请人:펜레코；
IPC主号:

专利说明:

Gel compositions
[4] This patent application is filed on October 29, 1998 under the name “gel composition” under the names of Lu Lu, Cunningham, Jack Cunningham, Jr., and Morrison David S. Morrison. One previously filed U.S. Provisional Application No. 60 / 106,094 is a continuation-in-part of U.S. Application No. 09 / 419,571, filed Oct. 18, 1999 under the name "gel composition". The disclosures of the aforementioned applications are all incorporated herein by reference.
[5] FIELD OF THE INVENTION The present invention relates to gel compositions that are gelled ester compositions, gelled ether compositions, gelled alcohol compositions, gelled natural fats and oil compositions, or combinations thereof and combinations of solvents, gelled ester compositions, gelled ethers A method of increasing the viscosity of compositions, gelled alcohol compositions, gelled natural fats and oil compositions.
[6] Many gel compositions are known in the art. Gel compositions have proven useful in a wide range of applications such as cosmetics, health and beauty, home care and industrial use.
[7] Gel compositions have been used in a variety of cosmetic and health and beauty applications. Some gel compositions have proven to be easy and effective vehicles or carriers for applying various active ingredients to the skin. Such active ingredients include sunscreens, limiting agents, deodorants, perfumes, cosmetics, emollients, insect repellents, pharmaceuticals and the like. Cosmetics and health and beauty products containing the gel composition, and products made primarily from the gel composition, may be in the form of liquids, soft gels, semisolids or solids. Rubbing liquid, soft gels, semi-solids or solids containing an effective amount of dissolved or dispersed active ingredient into the skin causes the gel composition to migrate in layer form on the skin surface to keep the active ingredient in a layer on the desired skin surface.
[8] For cosmetic and health and cosmetic applications, the gel composition should preferably have one or more of the following desirable properties: transparency, compatibility with the active ingredient, sustained release of the active ingredient, minimizing skin irritation And suspending ability of organic and inorganic materials such as coloring pigments, glitters, water, air, metal oxides, sunscreen active particles and fragrances and the like. For example, it is preferred if the gel itself can act as a sunscreen active ingredient when applied to sunscreen, and if the gel can provide suspension and sustained release when applied to cosmetics. In addition, the gel compositions used in cosmetics and health and beauty applications should exhibit moisturizing properties to the skin and water wash-off resistence, but not excessive syneresis.
[9] Gel compositions have also been used for a variety of home care applications. For home care applications, the gel composition should preferably provide one or more of the following desirable properties: transparency, compatibility with the active ingredient, sustained release of the active ingredient, and colored pigments, varnishes, water, air, metals Suspending ability of organic and inorganic materials such as oxides and fragrances. For example, when applied to an air freshener, important properties are sustained release and viscosity.
[10] In addition, gel compositions have been used for a variety of industrial applications. For industrial use, the gel composition should preferably provide one or more of the following desirable properties: suspension, moisture barrier, rheology, control of rheology, solubility ( solvency), sustained release, wettability, self-emulsification, transparency of the active or volatile components, compatibility with the active ingredients, etc. For example, in the paint industry, the important properties are suspension and sustained release, and in explosive emulsions, the important properties are suspension and fluidity control.
[11] Gel compositions are typically made by mixing one or more compounds to be gelled with a gelling agent. Subsequently, when the gel composition was combined or mixed with a relatively low viscosity solvent, the resulting gel composition was expected to have a lower viscosity than the original gel composition. However, for many cosmetic, health and beauty, home care and industrial uses, it may be desirable to mix or blend the gel composition with a solvent to produce a gel composition with increased viscosity.
[12] For example, when applied to drilling, the oil must be suspended and pumped to the surface. It is desirable to be able to increase the viscosity of the gel composition used for drilling purposes because gel compositions with low viscosity cannot suspend oil. In addition, when applied to an explosive emulsion, it is desirable to increase the viscosity of the gel composition used in the explosive emulsion because the gel composition having a low viscosity cannot be held in a gas and can be exploded. As an example also, for the drilling, formation and treatment of underground formations such as wells, the gel composition has a relatively low initial viscosity but it is often desirable or necessary to have a high viscosity once placed in the well hole or underground formation to be treated. Do.
[13] Therefore, there is a need to study how to increase the viscosity of the gel composition when combined with a low viscosity solvent. Gel compositions containing esters, ethers, alcohols and vegetable oils are less common than gelled mineral oils or gelled hydrocarbons. Therefore, there is also a need to study how to increase the viscosity of gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions.
[14] The present invention fulfills the above mentioned requirements in one or more of the following aspects. In one aspect, the invention relates to a gel composition referred to herein as a two-phase gel composition. This two-phase gel composition is a combination of at least two components. The first component is a gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or combinations thereof. The second component is a hydrophobic nonpolar solvent. The two-phase gel composition resulting from the mixture of the first and second components has a viscosity greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[15] Although one or more phosphate compounds may be present in other embodiments, in some embodiments the two-phase gel composition may be substantially free of phosphate compounds. Likewise, other two-phase gel compositions may contain one or more antioxidants, while some two-phase gel compositions may be substantially free of antioxidants. In some embodiments of the invention, the two-phase gel composition may optionally contain additional ingredients. In some embodiments, the additional component may be a suspension component. In other embodiments, additional ingredients may be active ingredients.
[16] In another aspect, the present invention relates to a method of increasing the viscosity of a gel composition. The method comprises (a) mixing a gelled ester composition, a gelled ether composition, a gelled alcohol composition, a gelled natural fat and oil composition, or a combination thereof with one or more hydrophobic nonpolar solvents to form a mixture; (b) heat the mixture; (c) stirring the mixture until the mixture is homogeneous; (d) cooling the mixture to form a two-phase gel composition. The resulting two-phase gel composition has a viscosity that is greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[17] In another aspect, the present invention relates to a method of increasing the viscosity of a gel composition. The method comprises (a) heating the gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or a combination thereof; (b) mixing the heated gel composition with one or more hydrophobic nonpolar solvents to form a mixture; (c) stirring the mixture until the mixture is homogeneous; (d) cooling the mixture to form a two-phase gel composition. The resulting two-phase gel composition has a viscosity that is greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[18] In another aspect, the present invention relates to a method of increasing the viscosity of a gel composition. This method comprises (a) heating one or more hydrophobic nonpolar solvents; (b) mixing the heated solvent with a gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or a combination thereof to form a mixture; (c) stirring the mixture until the mixture is homogeneous; (d) cooling the mixture to form a two-phase gel composition. The resulting two-phase gel composition has a viscosity that is greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[19] In another aspect, the present invention relates to a method of increasing the viscosity of a gel composition. This method comprises (a) heating one or more hydrophobic nonpolar solvents; (b) separately heating the gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or combinations thereof; (c) mixing the heated solvent with the heated gel composition to form a mixture; (d) stirring the mixture until the mixture is homogeneous; (e) cooling the mixture to form a two-phase gel composition. The resulting two-phase gel composition has a viscosity that is greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[20] In another aspect, the present invention relates to a method of increasing the viscosity of a gel composition. The method includes mixing a gelled ester composition, a gelled ether composition, a gelled alcohol composition, a gelled natural fat and oil composition, or a combination thereof with a hydrophobic nonpolar solvent to form a two-phase gel composition. The resulting two-phase gel composition has a viscosity that is greater than or equal to the viscosity of the individual components used to make the two-phase gel composition alone or in combination.
[21] The characteristics and advantages of embodiments of the present invention will become apparent from the following description.
[1] 1 is a graph of viscosity versus concentration for a two-phase gel composition according to one embodiment of the present invention.
[2] 2 is a graph of viscosity versus concentration for a two-phase gel composition according to another embodiment of the present invention.
[3] 3 is a graph of viscosity versus concentration for a two-phase gel composition according to another embodiment of the present invention.
[22] Embodiments of the present invention provide that the gel composition referred to herein as a two-phase gel composition can be obtained by blending or mixing a relatively low viscosity gelled composition with a relatively low viscosity solvent, resulting in a two-phase gel composition. It is based, in part, on the discovery that the viscosity of is greater than or equal to the viscosity of the individual components used alone or in combination to make it. The first component is a gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or combinations thereof. The second component is a relatively nonpolar hydrophobic solvent.
[23] The two-phase gel composition may comprise a first component (ie, gelled ester composition, gelled ether composition, gelled alcohol composition, gelled natural fat and oil composition, or combinations thereof), second component (solvent), and agent It has a viscosity equal to or greater than the sum of the first and second components. In some embodiments, the two-phase gel composition has a viscosity that is slightly greater than or equal to the first component, the second component, and / or the first and second components combined. In another embodiment, the viscosity of the two-phase gel composition is substantially greater than the sum of the viscosity of each component. The two-phase gel composition may be in the form of a liquid, solid, semisolid or gel. The gel may be a soft gel, semisolid gel, hard gel, or rubbery gel when the two-phase gel composition is in gel form.
[24] Although one or more phosphate compounds may be present in other embodiments, in some embodiments the two-phase gel composition may be substantially free of phosphate compounds. Likewise, other two-phase gel compositions may contain one or more antioxidants, while some two-phase gel compositions are substantially free of any antioxidants.
[25] In certain embodiments, the two-phase gel composition and the product prepared from such two-phase gel composition are translucent, cloudy or opaque. In certain other embodiments, the two-phase gel composition and the product made from such two-phase gel composition are transparent or substantially transparent. In certain other embodiments, the two-phase gel composition and the product made from such two-phase gel composition are translucent. Two-phase gel compositions and products made from these two-phase gel compositions each have many cosmetic, health and beauty, home care and industrial uses.
[26] The two-phase gel composition can optionally include additional components. Two-phase gel compositions provide suspension stability and sustained release for components that can be suspended. In some embodiments, the two-phase gel composition may optionally contain a suspending component. Examples of suitable suspending components include, but are not limited to, gases, non-hydrocarbon liquids, and solids that will be dispersed and substantially suspended or evenly dispersed into the two-phase gel composition. In some embodiments, the two-phase gel composition may further contain the active ingredient. Examples of suitable active ingredients include, but are not limited to, sunscreens, limiters, deodorants, perfumes, cosmetics, emollients, insect repellents, pesticides, herbicides, fungicides, plasticizers, insecticides and pharmaceuticals. The amount of additional components used in the two-phase gel composition depends on the desired properties of the final product in which the two-phase gel composition is used.
[27] Gel as used herein refers to a two-phase colloidal system containing liquids and solids in the form of thickened liquids, semisolids or solids. The gel also dissolves only in the presence of a liquid, either physically crosslinked by intertwined polymer chains or by the development of associative networks or insoluble domains or chemically crosslinked by covalent bonds. May mean a composition that is not. Gels are typically obtained by using a gelling agent. As used herein, the term "gelling agent" means a polymer dispersed in any suitable liquid, semisolid or solid material. The term "polymer" as used herein includes both homopolymers and copolymers. A single polymer is a polymer obtained by polymerizing one type of monomer, while a copolymer is a polymer obtained by polymerizing two or more types of monomer. A "block copolymer" is a polymer in which similar monomeric units are relatively long on the chain and are present in an alternating sequence. As used herein, the term "gel composition" means a gelling agent dispersed, dissolved or swollen in a suitable liquid, semisolid or solid material.
[28] As used herein, the term "two-phase gel composition" means a two-component system wherein the first component is the gelled component and the second component is the solvent. The use of the term two-phase gel composition does not require that the gel composition have two separate physical phases. As used herein, the term two-phase gel composition may be homogeneous (ie, single phase). In some embodiments, the two-phase gel composition is not reversely separated into the individual components used to prepare the two-phase gel composition. In other embodiments, the two-phase gel composition may be two, three, four, five or more phases. As used herein, the term "opaque" refers to the optical state of the medium in which the molecular aggregate is such that light cannot pass through it. Thus, the light transmittance through the opaque medium is substantially close to zero. On the other hand, the term "transparent" means an optical state through which light can pass and through which an object can be seen. As used herein, the term “transparent” includes all optical states that are not opaque. If only a small amount of light passes through the medium, the medium is considered transparent. Thus, clear gels and translucent gels are considered transparent.
[29] Gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil components are the only source of polymer for two-phase gel compositions. This component also means "gel base", "gelled base" or "gelled component". One or more gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oils may be used in embodiments of the present invention to form a two-phase gel composition. Although not necessary, the gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components are preferably relatively polar polymer concentrates having a relatively low viscosity. In some embodiments, the gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components are fluid at room temperature. Although gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil components may be present in the solid phase, for ease of handling the gelled components are preferably in the form of liquids or semisolids.
[30] The choice of gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components used in the two-phase gel composition depends on several factors. These factors include the desired properties of the two-phase gel composition, such as the viscosity, and the desired properties of the final product into which the two-phase gel composition can be incorporated, such as the viscosity, treatment temperature, mixing capability. The suitability of the raw material, and the like.
[31] The amount of gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil components present in the two-phase gel composition may be based on the desired properties of the two-phase gel composition, such as the desired viscosity, and Depending on the desired properties of the final product into which the phase gel composition can be incorporated, such as the desired viscosity, treatment temperature, mixing capacity, and the like.
[32] In some embodiments, small amounts of gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil components can be used to thicken the solvent component. In some embodiments, the amount of gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components present in the two-phase gel composition ranges from about 5 to about 95 weight percent of the two-phase gel composition. Can be. In certain other embodiments, the gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components are present in an amount of about 5 to about 60 weight percent of the two-phase gel composition. In another embodiment, the gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components are present in an amount of about 10 to about 40 weight percent of the two-phase gel composition. In yet another embodiment, the gelled ester, gelled ether, gelled alcohol, or gelled natural fat and oil components are present in an amount of about 20 to about 40 weight percent of the two-phase gel composition.
[33] Gelled esters, gelled ethers, gelled alcohols, and gelled natural fat and oil compositions and methods of making these compositions are described in detail in US Application Serial No. 09 / 419,571, filed Oct. 18, 1999, which is herein incorporated by reference. Included with reference to. In some embodiments, block copolymers capable of forming three-dimensional networks via physical crosslinking are used as gelling esters, gelling ethers, gelling alcohols, and gelling agents to form gelled natural fats and oil compositions do. Suitable block copolymers include at least one rigid block and one elastomeric block.
[34] Rigid blocks typically consist of polystyrene, polyethylene, polyvinyl chloride, phenolic resins, and the like; The elastomer block is composed of ethylene / butadiene copolymer, polyisoprene, polybutadiene, ethylene / propylene copolymer, ethylene-propylene / diene copolymer and the like. Accordingly, suitable diblock copolymers include, but are not limited to, styrene-ethylene / propylene copolymers, styrene-ethylene / butadiene copolymers, styrene-isoprene copolymers, styrene-butadiene copolymers, and mixtures thereof.
[35] Each polymer chain comprises two rigid blocks at the terminal or intermediate block that are elastomers. While this is the preferred triblock copolymer structure, triblock copolymers of two elastomeric end blocks and one rigid intermediate block may also be used. Suitable triblock copolymers include, but are not limited to, styrene-ethylene / propylene-styrene copolymers, styrene-ethylene / butadiene-styrene copolymers, styrene-isoprene-styrene copolymers, styrene-butadiene-styrene copolymers, and mixtures thereof It is not limited. Multiblock copolymers are similar to diblock or triblock copolymers, except that the multiblock copolymer includes additional elastomeric blocks and / or rigid blocks.
[36] In addition to the straight chain structure, branched homopolymers or copolymers may also be used to form gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions. Suitable side chain homopolymers or copolymers include, but are not limited to, radial and shaped polymers. It should also be noted that more than one functional group may be grafted onto the chain of any of the polymers mentioned above. In other words, any of the polymers described above can be modified by grafting. Suitable functional groups for grafting depend on the desired properties. For example, one or more ester groups, silane groups, silicone-containing groups, maleic anhydride groups, acrylamide groups, and acid groups can be grafted. In addition to grafting, these polymers can be lowered by their hydrogenation before being used as gelling agents.
[37] Many commercially available block copolymers can be used to form gelled ester compositions, gelled ether compositions, gelled alcohol compositions, and gelled natural fats and oil compositions. For example, several grades of copolymers sold under the trade name Kraton ^R by Kraton Company are used to form gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions. It can be used as a gelling agent. In addition, under the trade name Vector ^R (Dex nose (available from Dexco)), Septon ^R (Kuraray (available from Kuraray)), Tuftec ^R (available from Asahi (Asahi)) and Solprene ^R (raising four Industries Ars Negro Mex Copolymers commercially available from GRSA Industrias Negromex, SA de CV (INSA)) also gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oils. It can be used as a gelling agent to form the composition. US Pat. Nos. 5,221,534, 5,578,089 and 5,879,694 disclose block copolymers that can be used in embodiments of the present invention. The disclosures of all three patents are also incorporated herein by reference. Table 1 describes some of the commercially available block copolymers that can be used to form gelled ester compositions, gelled ether compositions, gelled alcohol compositions, and gelled natural fat and oil compositions. Further suitable block copolymers include polystyrene / polyester, polyether / polyamide, polyether / polyester, polyester / polyamide, polyether / polyurethane, polyester / polyurethane, poly (ethylene oxide) / poly ( Propylene oxide), nylon / rubber, and polysiloxane / polycarbonate.
[38] Table 1
[39] CopolymerBlock typePolystyrene Content (%)Explanation Kraton ^R G1702SEP28Hydrogenated Eblock Kraton ^R G1701SEP37Hydrogenated Eblock Kraton ^R G1780SEP7Hydrogenated polymer Kraton ^R G1650SEBS30Hydrogenated triblock Kraton ^R G1652SEBS30Hydrogenated triblock Kraton ^R D1101SBS + SP31Unsaturated triblock and diblock mixtures (85:15) Kraton ^R D1102SBS + SP28Unsaturated triblock + diblock (85:15) Kraton ^R D1133SBS + SP35Unsaturated triblock + diblock (66:34) Kraton ^R G1901SEBS30Triblock (functionally grafted with hydrogenation and 1.7% maleic anhydride) Septon ^R 1001SEP35Hydrogenated Eblock Vector ^R 6030SP30Hydrogenated Eblock Vector ^R 8550SBS29Hydrogenated triblock Vector ^R 2518PSBS31Hydrogenated triblock Solprene ^R 1430SB40Hydrogenated Eblock Kraton ^R D1160SIS + SI18Unsaturated triblock + diblock (80:20)
[40] Note: SEP stands for styrene / ethylene / propylene copolymer.
[41] SEBS means styrene / ethylene / butylene / styrene copolymer.
[42] SB means styrene / butadiene copolymer.
[43] SBS means styrene-butadiene-styrene copolymer.
[44] SI means styrene / isoprene copolymer.
[45] SIS means styrene / isoprene / styrene copolymer.
[46] Gelled esters used in two-phase gel compositions are obtained by gelling at least two components. The first component is an ester compound. The second component is a polymeric compound selected from the group consisting of triblock copolymers, shaped polymers, radial polymers, multiblock copolymers and combinations thereof. Optionally, the gelled ester composition further comprises one or more diblock copolymers. When diblock copolymers are used in combination with any of the triblock copolymers, shaped polymers, radial polymers and multiblock copolymers, the resulting gel composition is substantially free of mineral oil. In some embodiments, the gelled ester composition may be substantially free of phosphate compounds, but one or more of these compounds may be present in other embodiments.
[47] Any ester compound can be used in embodiments of the present invention to obtain a gelled ester composition. The ester is a compound comprising at least one carboxylate group [R-COO-, wherein R is hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl, substituted phenyl, or other organic radicals] Is defined. Suitable esters include monoesters, diesters, triesters and the like. For example, one class of suitable esters that can be gelled are represented by the following general formulas:
[48] And
[49] In the above formulas,
[50] n = 1, 2, 3 and 4; R ₁ is hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl or substituted phenyl; R ₂ is hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl, substituted phenyl, alkylene, phenylene, substituted alkylene or substituted phenylene and the like. Suitable groups for R ₂ depend on whether n is 1, 2, 3 or 4.
[51] Other classes of suitable esters that can be gelled to obtain a gelled ester composition are represented by the following general formula:
[52]
[53] Where
[54] R ₃ is alkylene, phenylene, substituted alkylene or substituted phenylene.
[55] Another class of suitable esters that can be gelled to obtain a gelled ester composition is represented by the following general formula:
[56]
[57] Where
[58] R ₄ , R ₅ and R ₆ are individually alkylene, phenylene, substituted alkylene or substituted phenylene; R ₇ , R ₈ and R ₉ are individually hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl or substituted phenyl.
[59] Preferred esters and their formulas are described in Table 2.
[60] TABLE 2
[61]
[62]
[63]
[64] Other suitable esters include, but are not limited to, the following compounds: acepiline methylsilanol mannuronate; Acetaminosalol; Acetylated cetyl hydroxyprolineate; Acetylated glycol stearate; Acetylated sucrose distearate; Acetylmethionyl methylsilanol elastinate; Acetyl tributyl citrate; Acetyl triethyl citrate; Acetyl trihexyl citrate; Allurites Moluccana ethyl ester; Allethrin; Allyl caproate; Amyl acetate; Amyl benzoate; Amyl salicylate; Arachidyl behenate; Arachidyl glycol isostearate; Arachidyl propionate; Ascorbyl dipalmitate; Alscoville palmitate; Ascorbyl stearate; Aspartame; Batyl isostearate; Batyl stearate; Bean palmitate; Behenyl beeswax; Behenyl behenate; Behenyl benzoate; Behenyl erucate; Behenyl isostearate; Behenyl / isostearyl beeswax; 1,2,4-benzenetriacetate; Benzoin (styrox benzoin) gum; Benzoxiquin; Benzyl acetate; Benzyl benzoate; Benzyl cinnamates; Benzyl hyaluronate; Benzyl laurate; Benzyl nicotinate; Benzylparabens; Benzyl salicylate; Beta-cytosteryl acetate; Look at the officialis Borago officinalis ) Ethyl ester; Butoxyethyl acetate; Butoxyethyl nicotinate; Butoxyethyl stearate; Butyl acetate, butyl acetyl ricinoleate; Butyl benzoate; Butyl benzyl phthalate; 2-t-butylcyclohexyl acetate; Butylene glycol dicaprylate / dicaprate; Butylene glycol montanate; Butyl ester of ethylene / MA copolymer; Butyl ester of PVM / MA copolymer; Butylglucoside caprate; Butyl isostearate; Butyl lactate; Butyl methacrylate; Butyl myristate; Butyloctyl beeswax; Butyloctyl benzoate; Butyloctyl canderylate; Butyloctyl oleate; Butyloctyl salicylate; Butyl oleate; Butyl PABA; Butyl parabens; Butyl phthalyl butyl glycolate; Butyl stearate; Butyl thioglycolate; Butyroyl trihexyl citrate; C18-36 acid glycol esters; C12-20 acid PEG-8 ester; Caffeine benzoate; Calcium panthene sulfonate; Calcium stearoyl lactylate; C18-28 alkyl acetates; C18-38 alkyl beeswax; C30-50 alkyl beeswax; C20-40 alkyl behenate; C18-38 alkyl C24-54 acid esters; C-8 alkyl ethyl phosphate; C18-38 alkyl hydroxystearoyl stearate; C12-13 alkyl lactate; C12-15 alkyl lactate; C12-13 alkyl octanoate; C12-15 alkyl octanoate; C12-15 alkyl salicylate; C18-36 alkyl stearate; C20-40 alkyl stearate; C30-50 alkyl stearate; C40-60 alkyl stearate; Caproyl ethyl glucoside; Capryloyl salicylic acid; Caprylyl butyrate; Castor oil benzoate; C10-30 cholesterol / lanosterol esters; Cellulose acetate; Cellulose acetate butyrate; Cellulose acetate propionate; Cellulose acetate propionate carboxylate; Ceteareth-7 stearate; Cetearyl behenate; Cetearyl canderylate; Cetearyl isononanoate; Cetearyl octanoate; Cetearyl palmitate; Cetearyl stearate; Cetyl acetate; Cetyl acetyl ricinoleate; Cetyl caprylate; Cetyl C12-15-pallet-9 carboxylate; Cetyl glycol isostearate; Cetyl isononanoate; Cetyl lactate; Cetyl laurate; Cetyl myristate; Cetyl octanoate; Cetyl oleate; Cetyl palmitate; Cetyl PCA; Cetyl PPG-2 isodecet-7 carboxylate; Cetyl ricinoleate; Cetyl ricinoleate benzoate; Cetyl stearate; C16-20 glycol isostearate; C20-30 glycol isostearate; C14-16 glycol palmitate; Chimil isostearate; Chymil stearate; Chlorogenic acid; Cholesteryl acetate; Cholesteryl / behenyl / octyldodecyl lauroyl glutamate; Cholesteryl butyrate; Cholesteryl dichlorobenzoate; Cholesteryl hydroxystearate; Cholesteryl isostearate; Cholesteryl isostearate carbonate; Cholesteryl lanoleate; Cholesteryl macadamiate; Cholesteryl nonanoate; Cholesteryl / octyldodecyl lauroyl glutamate; Cholesteryl oleate; Cholesteryl stearate; Cinnamil acetate; Synoxate; Citronelyl acetate; Coco-caprylate / caprate; Coco rapecidate; Cocoyl ethyl glucoside; Cooper PCA methylsilanol; Corylus Abellana ( Corylus avellanna ) Ethyl ester; C12-15 pallet-9 hydrogenation tallowate; C11-15 pallet-3 oleate; C12-15 pallet-12 oleate; C11-15 pallet-3 stearate; C11-15 pallet-12 stearate; Decyl isostearate; Decyl myristate; Decyl oleate; Decyl succinate; DMDM hydantoin dilaurate; Dextrin behenate; Dextrin laurate; Dextrin myristate; Dextrin palmitate; Dextrin stearate; Daacetin; Dibutyl adipate; Dibutyl oxalate; Dibutyl phthalate; Dibutyl sebacate; Di-C12-15 alkyl adipate; Di-C12-15 alkyl fumarate; Di-C12-13 alkyl maleate; Di-C12-13 alkyl tartrate; Di-C14-15 alkyl tartrate; Dicapryl adipate; Dicaprylyl maleate; Dicetearyl dimer dilinoleate; Dacetyl adipate; Dicetyl thiodipropionate; Dicoyl pentaerythryl distearyl citrate; Diethoxyethyl succinate; Diethyl acetyl aspartate; Diethylaminoethyl cocoate; Diethylaminoethyl PEG-5 cocoate; Diethylaminoethyl PEG-5 laurate; Diethylaminoethyl stearate; Diethyl aspartate; Diethylene glycol dibenzoate; Diethylene glycol diisononanoate; Diethylene glycol dioctanoate; Diethylene glycol dioctanoate / diisononanoate; Diethyl glutamate; Diethyl oxalate; Diethyl palmitoyl aspartate; Diethyl phthalate; Diethyl sebacate; Diethyl succinate; Digaloyl trioleate; Diglyceryl stearate maleate; Dihexyl adipate; Dihexyldecyl lauroyl glutamate; Dihydroabiethyl behenate; Dihydroabiethyl methacrylate; Dihydrocholesteryl butyrate; Dihydrocholesteryl isostearate; Dihydrocholesteryl macadamiate; Dihydrocholesteryl nonanoate; Dihydrocholesteryl octyldecanoate; Dihydrocholesteryl oleate; Dihydrozinate palmoyl hydroxyethylmonium methosulfate; Dihydrozinate tallow phthalate; Dihydrophytosteryl octyldecanoate; Dihydroxyethylamino hydroxypropyl oleate; Dihydroxyethyl soyamine dioleate; Diisobutyl adipate; Diisobutyl oxalate; Diisocetyl adipate; Diisodecyl adipate; Diisopropyl adipate; Diisopropyl dimer dilinoleate; Diisopropyl methyl cinnamates; Diisopropyl oxalate; Diisopropyl sebacate; Diisostearamidopropyl epoxypropylmonium chloride; Diisostearoyl trimethylolpropane siloxy silicate; Diisostearyl adipate; Diisostearyl dimer dilinoleate; Diisostearyl fumarate; Diisostearyl glutarate; Diisostearyl malt; Dilauret-7 citrate; Dilauryl thiodipropionate; Dimethicone copolyol acetate; Dimethicone copolyol adipate; Dimethicone copolyol almonddate; Dimethicone copolyol beeswax; Dimethicone copolyol behenate; Dimethicone copolyol benzoate; Dimethicone copolyol borageate; Dimethicone copolyol cocoa butyrate; Dimethicone copolyol Dhupa butyrate; Dimethicone copolyol hydroxystearate; Dimethicone copolyol isostearate; Dimethicone copolyol Kokum buterate; Dimethicone copolyol lactate; Dimethicone copolyol laurate; Dimethicone copolyol mango butyrate; Dimethicone copolyol meadowfoamate; Dimethicone copolyol mohwa butaterate; Dimethicone copolyol octyldodecyl citrate; Dimethicone copolyol oleate; Dimethicone copolyol phthalate; Dimethicone copolyol sal butaterate; Dimethicone copolyol shea butyrate; Dimethicone copolyol stearate; Dimethicone copoly undecylenate; Dimethiconol beeswax; Dimethiconol behenate; Dimethiconol borageate; Dimethiconol dupa butyrate; Dimethiconol fluoroalcohol dilinolenic acid; Dimethiconol hydroxystearate; Dimethiconol ellipe butate; Dimethiconol isostearate; Dimethiconol comum butaterate; Dimethiconol lactate; Dimethiconol mo and butyrate; Dimethiconol sal butate; Dimethiconol stearate; Dimethyl adipate; Dimethylaminoethyl methacrylate; Dimethyl brasylate; Dimethylcystinate; Dimethyl glutarate; Dimethyl maleate; Dimethyl oxalate; Dimethyl phthalate; Dimethyl succinate; Dimyristyl tartrate; Dimyristyl thiodipropionate; Dinooxynol-9 citrate; Dioctyl adipate; Dioctyl butamido triazone; Dioctyl dimer dilinoleate; Dioctyldodecet-2 lauroyl glutamate; Dioctyldodecyl adipate; Dioctyldodecyl dimer dilinoleate; Dioctyldodecyl dodecanedioate; Dioctyldodecyl fluoroheptyl citrate; Dioctyldodecyl lauroyl glutamate; Dioctyldodecyl stearoyl dimer dilinoleate; Dioctyldodecyl stearoyl glutamate; Dioctyl fumarate; Dioctyl maleate; Dioctyl maleate; Dioctyl phthalate; Dioctyl sebacate; Dioctyl succinate; Dioleoyl edtolmonium methosulfate; Dipalmitoyl hydroxyproline; Dipentaerythryl hexacaprylate / hexacaprate; Dipentaerythryl hexaheptanoate / hexacaprylate / hexacaprate; Dipentaerythryl hexahydroxystearate; Dipentaerythryl hexahydroxystearate / stearate / loginate; Dipentaerythryl hexaoctanoate / behenate; Dipentaerythryl pentahydroxystearate / isostearate; Diphenyl carbomethoxy acetoxy naphthopyran; Dipropyl adipate; Dipropylene glycol caprylate; Dipropylene glycol dibenzoate; Dipropylene glycol salicylate; Dipropyl oxalate; Disodium laureth-7 citrate; Disodium PEG-5 lauryl citrate sulfosuccinate; Disodium PET-8 ricinosuccinate; Disodium succinoyl glycyrrhetinate; Disodium 2-sulfolaurate; Disteret-2 lauroyl glutamate; Disteret-5 lauroyl glutamate; Distearyl thiodipropionate; Diethaloethylethyl hydroxyethylmonium methosulfate; Ditridecyl adipate; Ditridecyl dimer dilinoleate; Ditridecyl thiodipropionate; Dodecyl gallate; Erucyl arachidate; Erucil erucate; Erucyl oleate; Ethiodized oils; Ethoxydiglycol acetate; Ethoxyethanol acetate; Ethyl acetate; Ethyl almonddate; Ethyl apricot kernelate; Ethyl arachidonate; Ethyl aspartate; Ethyl avocadodate; Ethyl benzoate; Ethyl biotinate; Ethyl butylacetylaminopropionate; Ethyl cinnamate; Ethyl cyanoacrylate; Ethyl cyclhexy propionate; Ethyl dihydroxypropyl PABA; Diethyl diisopropylcinnamate; Ethylene brasylate; Ethylene carbonate; Ethyl esters of hydrolyzed animal proteins; Ethyl ester of hydrolyzed keratin; Ethyl ester of hydrolyzed silk; Ethyl ester of PVM / MA copolymer; Ethyl ferulate; Ethyl glutamate; Ethyl isostearate; Ethyl lactate; Ethyl laurate; Ethyl linoleate; Ethyl linolenate; Ethyl methacrylate; Ethyl methoxycinnamate; Ethyl methylphenyl glycidate; Ethyl minkate; Ethyl morrhuate; Ethyl myristate; Ethyl nicotinate; Ethyl oleate; Ethyl oleate; Ethyl PABA ethyl palmitate; Ethyl paraben; Ethyl PCA; Ethyl pelargonate; Ethyl persate; Ethyl phenylacetate; Ethyl ricinoleate; Ethyl serinate; Ethyl stearate; Ethyl thioglycolate; Ethyl urocanate; Ethyl wheat germane; Ethyl chimeninate; Etocrylene; Farnesyl acetate; Galactonolactone; Calbanum (Ferula Galvaniflua) Ferula galbaniflua )) oil; Gamma-nonalaxion; Geranyl acetate; Glucarolactone; Glucose glutamate; Glucose pentaacetate; Glucurolactone; Glyceret-7 benzoate; Glyceret-7 diisononanoate; Glyceret-8 hydroxystearate; Glyceret-5 lactate; Glycerol-25 PCA isostearate; Glyceret-7 triacetate; Glyceryl triacetyl hydroxystearate; Glyceryl triacetyl ricinoleate; Glycolamide stearate; Glycol / butylene glycol montanate; Glycol caterates; Glycol dibenhenate; Glycol dilaurate; Glycol dioctanoate; Glycol dioleate; Glycol distearate; Glycol dietholate; Glycol hydroxystearate; Glycol montanate; Glycol octanoate; Glycol oleate; Glycol palmitate; Glycol ricinoleate; Glycol salicylates; Glycol stearate; Glycol stearate SE; glycyretinyl stearate; Hexacosyl glycol isostearate; Hexanediol beeswax; Hexanediol distearate; Hexanetriol beeswax; Hexyldecyl benzoate; Hexyldecyl ester of hydrolyzed collagen; Hexyldecyl isostearate; Hexyldecyl laurate; Hexyldecyl octanoate; Hexyldecyl oleate; Hexyldecyl palmitate; Hexyldecyl stearate; Hexyldodecyl salicylate; Hexyl isostearate; Hexyl laurate; Hexyl nicotinate; Homosalate; Hydrogenated castor oil hydroxystearate; Hydrogenated castor oil isostearate; Hydrogenated castor oil laurate; Hydrogenated castor oil stearate; Hydrogenated castor oil triisostearate; Hydrogenated methyl abietate; Hydrogenated rosin; Hydroquinone PCA; Hydroxycetyl isostearate; Hydroxyoctacosanyl hydroxystearate; Inositol hexa-PCA; Iodopropynyl butylcarbamate; Isoamyl acetate; Isoamyl laurate; Isoamyl p-methoxycinnamate; Isobutyl acetate; Isobutylated lanolin oils; Isobutyl benzoate; Isobutyl myristate; Isobutyl palmitate; Isobutyl paraben; Isobutyl pelargonate; Isobutyl stearate; Isobutyl tallowate; Isocetearet-8 stearate; Isocetate-10 stearate; Isocetyl behenate; Isocetyl isodecanoate; Isocetyl isostearate; Isocetyl laurate; Isocetyl linoleoyl stearate; Isocetyl myristate; Isocetyl octanoate; Isocetyl palmitate; Isocetyl salicylate; Isocetyl stearate; Isocetyl stearoyl stearate; Isodedec-2 cocoate; Isodecyl citrate; Isodecyl cocoate; Isodecyl hydroxystearate; Isodecyl isononanoate; Isodecyl laurate; Isodecyl myristate; Isodecyl neopentanoate; Isodecyl octanoate; Isodecyl oleate; Isodecyl palmitate; Isodecyl paraben; Isodecyl salicylate; Isodecyl stearate; Isohexyl laurate; Isohexyl neopentanoate; Isohexyl palmitate; Isolauryl behenate; Isomerized jojoba oil; Isononyl ferulate; Isooctyl thioglycolate; Isopropyl acetate; Isopropyl arachidate; Isopropyl avocadodate; Isopropyl behenate; Isopropyl benzoate; Isopropylbenzyl salicylate; Isopropyl citrate; Isopropyl C12-15-pallet-9 carboxylate; Isopropyl hydroxystearate; Isopropyl isostearate; Isopropyl hohobate; Isopropyl lanoleate; Isopropyl laurate; Isopropyl linoleate; Isopropyl myristate; Isopropyl oleate; Isopropylparabens; Isopropyl PPG-2-isodecet-7 carboxylate; Isopropyl ricinoleate; Isopropyl sorbate; Isopropyl stearate; Isopropyl tallowate; Isopropyl thioglycolate; Isosorbide laurate; Isostearet-10 stearate; Isostearyl avocadodate; Isostearyl behenate; Isostearyl benzoate; Isostearyl erucate; Isostearyl isononanoate; Isostearyl isostearate; Isostearyl isostaroyl stearate; Isostearyl lactate; Isostearyl laurate; Isostearyl myristate; Isostearyl neopentanoate; Isostearyl octanoate; Isostearyl palmitate; Isostearyl stearoyl stearate; Isotridecyl isononanoate; Isotridecyl laurate; Isotridecyl myristate; Jojoba (Northus Chinensis) BuxusChinensis )) oil; Jojoba esters; Kojic dipalmitate; Rannet-9 acetate; Rannet-10 acetate; Rannet-4 phosphate; Lanolin linoleate; Lanolin ricinoleate; Lauret-2 acetate; Laureth-2 benzoate; Laureth-6 citrate; Laureth-7 citrate; Laureth-2 octanoate; Laureth-7 tartrate; Lauroyl ethyl glucoside; Lauroyl lautyl acid; Lauryl behenate; Lauryl cocoate; Lauryl isostearate; Lauryl lactate; Lauryl methacrylate; Lauryl myristate; Lauryl octanoate; Lauryl oleate; Lauryl palmitate; Lauryl stearate; Linallyl acetate; Linoleyl lactate; Madecassicoside; Mannitol laurate; Mannitan oleate; Menthyl acetate; Menthyl anthranilate; Menthyl lactate; Menthyl PCA; Menthyl salicylate; Methoxyisopropyl acetate; Methoxy-PEG-7 rutinyl succinate; Methyl acetate; Methyl acetylrisinoleate; Methyl anthranilate; Methyl behenate; Methyl benzoate; Methyl caproate; Methyl caprylate; Methyl caprylate / caprate; Methyl cocoate; 6-methyl comarin; Methyl dehydroabiate; Methyl dihydroaviate; Methyldihydrojasmonate; Methyl glutet-20 benzoate; Methyl glucose dioleate; Methyl glucose isostearate; Methyl glucose laurate; Methyl glucose sesquicaprylate / sesquicaprate; Methyl glucose sesquicocoate; Methyl glucose sesquiisostearate; Methyl glucose sesquilaurate; Methyl glucose sesquioleate; Methyl glucose sesquistearate; Methyl glycyrrhizate; Methyl hydrogenated rosinate; Methyl hydroxystearate; Methylisostearate; Methyl laurate; Methyl linoleate; Methyl 3-methylresorylate; Methyl myristate; Methyl nicotinate; Methyl oleate; Methyl palmate; Methyl palmitate; Methylparabens; Methyl pelargonate; Methyl ricinoleate; Methyl rosinate; Methyl salicylate; Methylsilanol acetylmethionate; Methylsilanol carboxymethyl theophylline; Methylsilanol carboxymethyl theophylline alginate; Methylsilanol hydroxyproline; Methylsilanol hydroxyproline aspartate; Methylsilanol mannuronate; Methylsilanol PCA; Methyl soyate; Methyl stearate; Methyl thioglycolate; Monosaccharide lactate condensates; Miret-3 caprate; Miret-3 laurate; Mirette-2 myristate; Mirette-3 myristate; Miret-3 octanoate; Miret-3 palmitate; Myristoyl ethyl glucoside; Myristoyl lauryl acid; Myristyl isostearate; Myristyl lactate; Myristyl lignocerate; Myristyl myristate; Myristyl octanoate; Myristyl propionate; Myristyl salicylate; Myristyl stearate; Neopentyl glycol dicaprate; Neopentyl glycol dicaprylate / dicaprate; Neopentyl glycol dicaprylate / difelargonate / dicaprate; Neopentyl glycol diheptanoate; Neopentyl glycol diisostearate; Neopentyl glycol dilaurate; Neopentyl glycol dioctanoate; Nonyl acetate; Nofil acetate; Octacosanyl glycol isostearate; Octocrylene; Octyl acetoxystearate; Octyl benzoate; Octyl caprylate / caprate; Octyl cocoate; Octyldecyl oleate; Octyldodecyl behenate; Octyldodecyl benzoate; Octyldodecyl erucate; Octyldodecyl hydroxystearate; Octyldodecyl isostearate; Octyldodecyl lactate; Octyldodecyl lanoleate; Octyldodecyl meadowfoamate; Octyldodecyl myristate; Octyldodecyl neodecanoate; Octyldodecyl neopentanoate; Octyldodecyl octanoate; Octyldodecyl octyldodecanoate; Octyldodecyl oleate; Octyldodecyl oleate; Octyldodecyl ricinoleate; Octyldodecyl stearate; Octyldodecyl steroyl stearate; Octyl gallate; Octyl hydroxystearate; Octyl hydroxystearate benzoate; Octyl isononanoate; Octyl isopalmitate; Octyl isostearate; Octyl laurate; Octyl linoleylyl stearate; Octyl methoxycinnamate; Octyl myristate; Octyl neopentanoate; Octyl octanoate; Octyl oleate; Octyl palmitate; Octyl PCA; Octyl pelargonate; Octyl salicylate; Octyl stearate; Oleoyl ethyl glucoside; Olet-2 benzoate; Oleyl acetate; Oleic arachidate; Oleic erucate; Oleyl ethyl phosphate; Oleyl lactate; Oleyl lanoleate; Oleyl linoleate; Oleyl myristate; Oleyl oleate; Oleyl phosphate; Oleyl stearate; Oryzanol; Ozonated jojoba oil; Palmitoyl canniline; Palmitoyl inulin; Palmitoyl myristyl serinate; Panthetin; Panthenyl ethyl ester acetate; Panthenyl triacetate; PCA glyceryl oleate; Pe palmitate; PEG-18 castor oil dioleate; PEG-5 DMDM Hydantoin Oleate; PEG-15 DMDM Hydantoin Stearate; PEG-30 dipolyhydroxystearate; PEG-20 hydrogenated castor oil isostearate; PEG-50 hydrogenated castor oil isostearate; PEG-20 hydrogenated castor oil triisostearate; PEG-20 mannitol laurate; PEG-20 methyl glucose distearate; PEG-80 methyl glucose laurate; PEG-20 methyl glucose sesquicaprylate / sesquicaprate; PEG-20 methyl glucose sesquilaurate; PEG-5 oleamide dioleate; PEG-150 pentaerythritol tetrastearate; PEG-3 / PPG-2 glyceryl / sorbitol hydroxystearate / isostearate; PEG-4 proline linoleate; PEG-4 proline linoleate; PEG-8 propylene glycol cocoate; PEG-55 propylene glycol oleate; PEG-25 propylene glycol stearate; PEG-75 propylene glycol stearate; PEG-120 propylene glycol stearate; PEG-40 sorbitol hexaoleate; PEG-50 sorbitol hexaoleate; PEG-30 sorbitol tetraoleate laurate; PEG-60 sorbitol tetrastearate; PEG-5 tricapryl citrate; PEG-5 tricetyl citrate; PEG-5 trilauryl citrate; PEG-5 trimethylolpropane trimyristate; PEG-5 trimyristyl citrate; PEG-5 tristearyl citrate; PEG-6 undecylenate; Pentadecaracion; Pentaerythritol dioleate; Pentaerythryl distearate; Pentaerythritol hydrogenated rosinate; Pentaerythryl isostearate / caprate / caprylate / adipate; Pentaerythrityl rosinate; Pentaerythryl stearate; Pentaerythritol stearate / caprate / caprylate / adipate; Pentaerythritol stearate / isostearate / adipate / hydroxystearate; Pentaerythryl tetraaviate; Pentaerythryl tetraacetate; Pentaerythryl tetrabehenate; Pentaerythryl tetrabenzoate; Pentaerythritol tetracaprylate / tetracaprate; Pentaerythrityl tetracocoate; Pentaerythryl tetraisononanoate; Pentaerythryltetralaurate; Pentaerythritol tetramyristate; Pentaerythritol tetraoctanoate; Pentaerythritol tetraoleate; Pentaerythryl tetrafellargonate; Pentaerythryl tetrastearate; Pentaerythritol trioleate; Phenethyl acetate; Phenolphthalein; Phenoxyethylparabens; Phenyl benzoate; Phenylparabens; Phenyl salicylate; Phyllosteryl macadamite; Poloxamer 105 benzoate; Poloxamer 182 dibenzoate; Polycaprolactone; Polydimethylaminoethyl methacrylate; Polyethyl acrylate; Polyethylglutamate; Polyethyl methacrylate; Polymethyl acrylate; Polymethylglutamate; Polysorbate 80 acetate; Polyvinyl acetate; Potassium butylparaben; Potassium decet-4 phosphate; Potassium ethylparaben; Potassium methylparabens; Potassium propylparaben; PPG-2 isoseret-20 acetate; PPG-14 laureth-60 alkyl dicarbamate; PPG-20 methyl glucose ether acetate; PPG-20 methyl glucose ether distearate; PPG-2 myristyl ether propionate; PPG-14 Palmmet-60 alkyl dicarbamate; PPG-15 steryl ether benzoate; Pregnenolone acetate; Propyl acetate; Propyl benzoate; Propylene carbonate; Propylene glycol alginate; Propylene glycol behenate; Propylene glycol caprylate; Propylene glycol cetet-3 acetate; Propylene glycol cetet-3 propionate; Propylene glycol citrate; Propylene glycol cocoate; Propylene glycol dicaprate; Propylene glycol dicaproate; Propylene glycol dicaprylate; Propylene glycol dicocoate; Propylene glycol diisononanoate; Propylene glycol diisostearate; Propylene glycol dilaurate; Propylene glycol dioctanoate; Propylene glycol dioleate; Propylene glycol dipellagonate; Propylene glycol distearate; Propylene glycol dioundecanoate; Propylene glycol hydroxystearate; Propylene glycol isocetate-3 acetate; Propylene glycol isostearate; Propylene glycol laurate; Propylene glycol linoleate; Propylene glycol linolenate; Propylene glycol myristate; Propylene glycol myristyl ether acetate; Propylene glycol oleate; Propylene glycol oleate SE; Propylene glycol ricinoleate; Propylene glycol soyate; Propylene glycol stearate; Propylene glycol stearate SE; Propyl gallate; Propylparabens; Pyrivate; Pyridoxine dicaprylate; Pyridoxine dilaurate; Pyridoxine dioctenoate; Pyridoxine dipalmitate; Pyridoxine glycyrrhetinate; Pyridoxine tripalmitate; Raffinose myristate; Raffinose oleate; Resorcinol acetate; Retinyl acetate; Retinyl linoleate; Retinyl palmitate; Retinyl propionate; Riboflavin tetraacetate; Ribonolaclone; Rosin acrylate; Siloxane triol phytate; Siliboom Marianum Silybum marianum ) Ethyl ester; Sodium behenoyl lactylate; Sodium butylparaben; Sodium caproyl lactylate; Sodium cocoyl lactylate; Sodium dilauret-7 citrate; Sodium ethylparaben; Sodium ethyl 2-sulfolaurate; Sodium isostaroyl lactylate; Sodium laureth-7 tartrate; Sodium lauroyl lectylate; Sodium methylparaben; Sodium methyl 2-sulfolaurate; Sodium oleoyl lactylate; Sodium pantheein sulfonate; Sodium phytate; Sodium propylparaben; Sodium stearoyl lactylate; Sorbet-2 cocoate; sorbet-6 hexastearate; Sorbet-3 isostearate; Sorbitol acetate; Soybean Palmitate; Soy sterol acetate; Stearamide DEA-distearate; Stearamide DIBA-stearate; Stearamide MEA-stearate; Stearet-5 stearate; Stearoyl lactic acid; Stearyl acetate; Stearyl acetyl glutamate; Stearyl beeswax; Stearyl behenate; Stearyl benzoate; Stearyl caprylate; Stearyl citrate; Stearyl erucate; Stearyl glycol isostearate; Stearyl glycyrrhetinate; Stearyl heptanoate; Stearyl lactate; Stearyl linoleate; Stearyl octanoate; Stearyl stearate; Stearyl stearoyl stearate; Sucrose acetate isobutyrate; Sucrose benzoate; Sucrose cocoate; Sucrose dilaurate; Sucrose distearate; Sucrose laurate; Sucrose myristate; Sucrose octaacetate; Sucrose oleate; Sucrose palmitate; Sucrose polybehenate; Sucrose Polycottonseedate; Sucrose polylaurate; Sucrose polylinoleate; Sucrose polypalmate; Sucrose polysoate; Sucrose polystearate; Sucrose ricinoleate; Sucrose stearate; Sucrose tetrastearate triacetate; Sucrose tribehenate; Sucrose tristearate; Tallowoil ethyl glucoside; tannin; TEA-lauroyl lactylate; Telmessteine; Terpineol acetate; Tetrabutyl phenyl hydroxybenzoate; Tetradecylethylacyl stearate; Tetrahexyldecyl ascorbate; Tetrahydrofurfuryl acetate; Tetrahydrofurfuryl ricinoleate; Tocophersolane; Tocopheryl acetate; Tocopheryl linoleate; Tocopheryl linoleate / oleate; Tocopheryl nicotinate; Tocopheryl succinate; Tributyl citrate; Tri-C12-13 alkyl citrate; Tri-C14-15 alkyl citrate; Tricaprylyl citrate; Tridecyl behenate; Tridecyl cocoate; Tridecyl erucate; Tridecyl isononanoate; Tridecyl laurate; Tridecyl myristate; Tridecyl neopentanoate; Tridecyl octanoate; Tridecyl stearate; Tridecyl stearoyl stearate; Tridecyl trimellitate; Triethyl citrate; Triethylene glycol hydrogenated rosinate; Trihexyldecyl citrate; Triisocetyl citrate; Triisopropyl citrate; Triisopropyl trilinoleate; Triisostearyl citrate; Triisostearyl trilinoleate; Trilactin; Trilauryl citrate; Trimethylolpropane tricaprylate / tricaprate; Trimethylolpropane tricocoate; Trimethylolpropane trilaurate; Trimethylolpropane trioctanoate; Trimethylolpropane tristearate; Trimethyl fentanyl diisobutyrate; Trioctyl citrate; Trioctyldodecyl borate; Trioctyl trimellitate; Trioleyl citrate; TriPABA panthenol; Tripropylene glycol citrate; Tristearyl citrate; Tristearyl phosphate; Vinyl acetate; And yeast palmitate.
[65] Gelled ether compositions used in two-phase gel compositions are obtained by gelling at least two components. The first component is an ether compound. The second component may be a polymer compound selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers and combinations thereof. In general, ether compounds are represented by the following general formula:
[66] R-O-R '
[67] Where
[68] R and R 'individually include but are not limited to hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl, substituted phenyl and the like. Preferred ethers include, but are not limited to, dicaprylyl ether and octyl methoxycinnamate. Dicaprylyl ether is represented by the formula:
[69] C ₈ H ₁₇ -OC ₈ H ₁₇
[70] Other suitable ethers include the following compounds: anetol; p-anidic acid; Batyl alcohol; Batyl isostearate; Batyl stearate; Benzyl hemiformal; 1,3-bis- (2,4-diaminophenoxy) propane; Butoxyethyl acetate; Butoxyethyl nicotinate; Butoxyethyl stearate; Butoxypropanol; 2-t-butylcyclohexyloxybutanol; Butyl glucoside; Butylglucoside caprate; Butyl methoxydibenzoylmethane; Caprylyl / capryl glucoside; Capsaicin; Carboxymethyl chitin; Carboxymethyl chitosan succinimide; Carboxymethyl dextran; Cetearyl glucoside; Cetyl glyceryl ether; Cetyl-PG hydroxyethyl decanamide; Cetyl-PG hydroxyethyl palmitamide; Chymil alcohol; Chimil isostearate; Chymil stearate; Chlorphenesine; Synoxate; Cocamidopropyl lauryl ether; Coset-4 glucoside; Coco-glucoside; Dibenzylidene sorbitol; Dicetyl ether; Dichlorophenyl imidazolidioxolane; Dimethicone copolyol butyl ether; dimethicone copolyol ethyl ether; Dimethicone copolyol methyl ether; Dimethyl hexahydronaphthyl dihydroxymethyl acetal; Dimethyl isosorbide; Dioleyl tocopheryl methylsilanol; Diosmin; Disodium cetyl phenyl ether disulfonate; Disodium decyl phenyl ether disulfonate; Disodium lauryl phenyl ether disulfonate; Distachy glyceryl ether; Distearyl ether; Ethoxydiglycol acetate; Ethoxyheptyl bicyclooctanone; 7-ethylbicyclooxazolidine; Ethyl methoxycinnamate; Ethyl methylphenyl glycidate; Ethyl phenethyl acetal; Eucalyptol; Eugenol; Ferulic acid; Glyceryl octanoate dimethoxycinnamate; Glycofurol; Hexamethylindanopyran; Hexamidine; Hexamidine diparaben; Hexamidine parabens; Hydrogenated ethylbicycloheptane guoacol; p-hydroxyanisole; Hydroxydecyl maltitol; Hydroxyethyl glyceryl oleate / stearate; Hydroxyethyl palmityl oxyhydroxypropyl palmitamide; Hydroxyethyl sorbitol; Hydroxymethoxybenzyl pelargonamide; Hydroxypropyl starch phosphate; Hydroxystearyl cetyl ether; Isobutyl methyl tetrahydropropanol; Isoeugenol; Isonron group olefin epoxide; Isopropyl hydroxycetyl ether; Isostearamide propyl epoxypropyl dimonium chloride; Isostearyl glyceryl ether; Isostearyl glyceryl pentaerythritol ether; Lauryl polyglyceryl-6 cetearyl glycol ether; Melatonin; Menton glycerin acetal; Methoxyindan; Methoxyisopropyl acetate; Methoxymethylbutanol; Methoxypropylgluconamide; Methylal; Ethyl eugenol; Methyl hexyl ether; Methylsilanol ascorbate; Myristyl-PG hydroxyethyl decanamide; 4-nitroguaiacol; Octoxyglycerin; Octoxyglyceryl behenate; Octoxyglyceryl palmitate; Octyl glyceryl palmitate; Oleyl glyceryl ether; Panthenyl ethyl ether; Panthenyl ethyl ether acetate; Panthenyl hydroxypropyl stearmonium chloride; PEG-3 2,2-di-p-phenylenediamine; PEG-4 detalow ether; PEG-150 pentaerythritol tetrastearate; p-phenetidine; Phenoxyethanol; Phenoxyethylparabens; Phenoxyisopropanol; Polyglycerin-3; Polyglycerin-4; Polyglycerin-6; Polyglycerin-10; Polyglyceryl-3 cetyl ether; Polyglyceryl-3 decyltetradecyl ether; Polyglyceryl-3 hydroxylauryl ether; Polyglyceryl-2 lanolin alcohol ethers; Polyglyceryl-4 lauryl ether; Polyglyceryl-2 oleyl ether; Polyglyceryl-4 oleyl ether; Polyglyceryl sorbitol; Polyvinyl methyl ether; Polyvinyl stearyl ether; PPG-9 diglyceryl ether; PPG-l-PEG-9 lauryl glycol ether; Propylene glycol myristyl ether; Quacin; Silanetriol trehalose ether; TEA-lauryl ether; Tetrahydrodiferulomimethane; Thiodiglycol; Triclosan; Triethylene glycol; Trihydroxypalmitamidohydroxypropyl myristyl ether; Trimethoxycaprylylsilane; Troxerotin; And ubiquinone.
[71] Gelled alcohol compositions used in two-phase gel compositions are obtained by gelling at least two components. The first component is an alcohol compound. The second component may be a polymer compound selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers and combinations thereof. Gels of the following general formulas can be gelled to obtain gelled alcohol compositions:
[72] R-OH
[73] Where
[74] R represents any organic functional group, including but not limited to hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl, substituted phenyl and the like. Preferred alcohols include, but are not limited to, isostearyl alcohol and octyl dodecanol. Other suitable alcohols include, but are not limited to, the following compounds: abiethyl alcohol; Arachidyl alcohol; Batyl alcohol; Behenyl alcohol; Benzyl alcohol; Bishydroxyethyl biscetyl malonamide; Borneol; 2-t-butylcyclohexyloxybutanol; Butyl octanol; C9-11 alcohol; C12-13 alcohol; C12-15 alcohol; C12-16 alcohol; C14-15 alcohol; C-20-40 alcohol; C30-50 alcohol; C40-60 alcohol; C18-38 alkyl hydroxystearoyl stearate; Camphor cyclohexanol; Caproyl spinosine; Caprylic alcohol; Caprylyl glycol; CD alcohol 19; Ceramide 1; Ceramide 2; Ceramide 3; Ceramide 4; Ceramide 5; Ceramide 1A; Ceramide 6 II; Cetearyl alcohol; Cetyl alcohol; Cetyl arachidol; Cetyl glycol; C9-13 fluoroalcohol; C14-18 glycol; C15-18 glycol; C18-30 glycol; C20-30 glycol; Chymil alcohol; Chlorphenesine; Cholecleciferol; cholesterol; Cinnamil alcohol; Citronellol; Coconut alcohol; Decyl alcohol; Decyltetradecanol; 7-dehydrocholesterol; Dichlorobenzyl alcohol; Dihydrocholesterol; Dihydrolanosterol; Dihydroxyacetone; Dihydroxyethylamino hydroxypropyl oleate; 2,6-dimethyl-7-octen-2-ol; Dimethyl octindiol; Dimethyl phenylpropanol; Dodecylhexadecanol; Dodecyltetradecanol; Ergocalciferol; Ethyl hexanediol; Farnesol; Galactonolactone; Geraniol; Glycyrrhetinic acid; Glycyrrhizinic acid; Heptyl undecanol; Hexacosyl glycol; 3-hexenol; Hexyl alcohol; Hexyldecanol; Hexyldecyloctadecanol; Hexylene glycol; Hinokithiol; Hydroabiethyl alcohol; Hydrogenated ethylbicyclolone guai alcohol; Hydrogenated tallow alcohol; Hydrolyzed glycyrizinates; Hydroxycapric acid; Hydroxycaproyl phytospinosine; Hydroxycaprylic acid; Hydroxycapryloyl phytospinosine; Hydroxyethyl palmityl oxyhydroxypropyl palmitamide; Hydroxylauric acid; Hydroxylauroyl phytospinosine; Hydroxymethyl dioxazacyclooctane; Hydroxyproline; Hydroxystearyl cetyl ether; Jojoba alcohol; Lactoyl phytospinosine; Lanolin alcohols; Lauryl alcohol; Lauryl glycol; Linalool; p-mentan-7-ol; menthol; Menton glycerin acetal; 3-methylamino-4-nitrophenoxyethanol; Methyl glycysilicate; Methylsilanol hydroxyproline; Myrisil alcohol; Myristyl alcohol; Nicotinyl alcohol; Nicotinyl tartrate; 3-nitro-4-aminophenoxyethanol; Octacosanyl glycol; Octoxyglycerin; Octoxyglyceryl behenate: octyldodecanol; 2-oamido-1,3-octadecanediol; Oleyl alcohol; Palm alcohol; Palm kernel alcohol; Palmitamidohexadecanediol; Panthenol; Panthenyl ethyl ether; Panthenyl hydroxypropyl stearmonium chloride; Pentadecyl alcohol; Pentylene glycol; Phenethyl alcohol; Phenoxyethanol; Phenoxyisopropanol; Phenylisohexanol; Phenylpropanol; Phytospinosine; Polyvinyl alcohol; Propanediol; Propyl alcohol; Propylene glycol; Pyridoxine glycyrrhetinate; Retinol; Ribonolactone; N-stearoyl-dihydrocingosin; Stearyl alcohol; Stearyl glycol; Tallow alcohol; Terpineol; Tetradecylecosanol; Tetradecyloctadecanol; Tetrahydrofurfuryl alcohol; Tetramethyl cyclopentene butenol; Tetramethyl decinediol; Tridecyl alcohol; Trimethylhexanol; Troxerotin; Undecet-3; undecylenyl alcohol; And undecylpentadecanol.
[75] Gelled natural fat and oil compositions used in two-phase gel compositions are obtained by gelling at least two components. The first component is a natural fat and oil compound. The second component may be a polymer compound selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers and combinations thereof.
[76] "Natural fats and oils" refer to glyceryl esters (ie triglycerides) of fatty acids often found in animal or plant tissues, including those hydrogenated to reduce or eliminate unsaturation. Natural fats or oils include linseed oil, soybean oil, sunflower oil, corn oil, sesame oil, olive oil, castor oil, coconut oil, palm oil, peanut oil, jojoba oil and macadamia nut oil.
[77] Selected natural fats and oils are represented by the following general formula:
[78]
[79] Where
[80] R, R 'and R "may be the same or different fatty acid radicals. Examples of suitable natural fats and oils include, but are not limited to, the following compounds: Adansonla Digitata oil; Apricot ( Prunus Armeniaca ) Nuclear oil; Argania Spinosa oil; Argemone Mexicana oil; Avocado ( Persea Gratissima ) oil; Babassu ( Orbignya Olelfera ) Oil; Balm Mint ( Melissa Officinalis ) Seed Oil; Bitter Almond (Prunus Ami) Prunus Amygdalus Amara ) Oil; Bitter Cherry ( Prunus Cerasus ) Oil; Black Currant ( Ribes Nigrum ) Oil; Borage (Borage) Operational leases during the day (Borago Officinalis)) Oil; Brazilian (Brazil) (Toledo Bell Tia Excel Inc. (Bertholletia Excelsa)) nut oil; bureudok (Burdock) (Arc tium Rafa (Arctium Lappa)) Oil; Butter; C12-18 acid triglycerides; knife pilrum Taka Mach car (Calophyllum Tacamahaca) oil; Camellia shi (Camellia Kissi) oil; Camellia Olay Blow (Camellia Oleifera) seed Oil; canola (canola) oil; caprylic / Capric / router rigs triglycerides; caprylic / Capric / linoleic triglycerides; caprylic / capric / mystic / stearic triglycerides; caprylic / capric / stearic triglycerides; caprylic / capric triglycerides; Caraway (Carum Carby) ( Carum Carvi )) seed oil; Carrot ( Daucus Carota Sativa ) oil; Cashew ( Anacardium Occidentale ) nut oils; Castor oil benzoate; Castor ( Ricinus Communis ) oils; Cephalins ; Chaulmoogra ( Taraktogenos Kurzii ) oil, Chia ( Salvia Hispanica ) oil; Cocoa ( Theobrama Cocao ) butter; Coconut ( Cocos Nucifera ) oils; Cod Liver oil; Coffee ( Coffea Arabica ) oil; Corn ( Zea Mays ) Germ oil; Corn ( Zea Mays ) oil; Cotton ( Gossypium ) seed oil; C10-18 triglycerides; Cucumber ( Cucumis Sativus ) oil; Dog Rose ( Rosa Canina ) hip oil; Egg oil; Emu oil; Epoxidized soybean oil; Evening primrose ( Oenothera Biennis ) oil; Fish liver oil; Gevuina Avellana oil; Glyceryl triacetyl hydroxystearate; Glyceryl triacetyl ricinoleate; Glycolipids; Glycosphingolipids; Goat Butter; Grape ( Vitis Vinifera ) seed oil; Hazel ( Croylus Americana ) nut oils; Hazel ( Corylus Aveilana ) nut oil; Human placental lipids; Hybrid Safflower ( Carthamus Tinctorius ) Oils; Hybrid Sunflower (Hlianthus Annuus ) Seed Oil; Hydrogenated canola oil; Hydrogenated castor oil; Hydrogenated castor oil laurate; Hydrogenated castor oil triisostearate; Hydrogenated coconut oil; Hydrogenated cotton seed oil; Hydrogenated C12-18 triglycerides; Hydrogenated fish oils; Hydrogenated Lard; Hydrogenated Menhaden oil; Hydrogenated milk lipids; Hydrogenated mink oils; Hydrogenated olive oil; Hydrogenated Orange Roughy oil; Hydrogenated palm kernel oil; Hydrogenated palm oil; Hydrogenated chilled crude oil; Hydrogenated Rape seed oil; Hydrogenated shark liver oil; Hydrogenated soybean oil; Hydrogenated tallow; Hydrogenated vegetable oils; Isatis Tinctoria oil; Yulmu ( Coix Lacryma-Jobi ) oil; Kiwi ( Actinidia Chinensis ) seed oil; Kukui ( Aleurites Moluccana ) nut oils; lard; Lauric / palmitic / oleic triglycerides; Linseed ( linum usitatissiumum ) oil; Lupin ( Lupinus Albus ) oil; Macadamia nut oil; Macadamia Ternifolia Seed Oil; Macadamia Integrifolia Seed Oil; Maleated soybean oil; Mango ( Mangifera Indica ) seed oil; Marmot oil; Meadows carcinoma (rimnan test Alba (Limnanthes Alba)) Oil; Menhaden oil; Milk lipids; Mink work; Moringa Pterygosperma oil; Mortierella oil; Musk rose ( Rosa Moschata ) seed oil; Neatsfoot oil; Neem ( Melia Azadirachta ) seed oil; Oat ( Avena Sativa ) nuclear oil; Oleic / linoleic triglycerides; Oleic / palmitic / lauric / mystic / linoleic triglycerides; Oleostearin; Olive ( Olea Europaea ) husk oil; Olive ( Olea Europaea ) oil; Omental Lipdis; Orange Roughy Oil; Ostrich oil; Oxidized corn oil; Palm ( Elaeis Guineensis ) nuclear oil; Palm ( Elaeis Guineensis ) oil; Passionflower ( Passiflora Edulis ) oil; Peach ( Prunus Persica ) nuclear oil; Peanut ( Arachis Hypogaea ) oil; Pecan ( Carya Illinoensis ) oil; Pengawar Djambi ( Cibotium Barometz) oil; Phospholipids; Pistachio ( Pistacia Vera ) nut oils; Placenta lipids; Poppy (Papaber Orientale ) Oil; Pumpkin ( Cucurbita Pepo ) Seed Oil; Quinoa ( Chenopodium Quinoa ) Oil; Rape (Brassica Campestries) ( Brassica Campestris )) seed oil; rice ( Oryza Sativa ) bran oil; rice ( Oryza Sativa ) endosperm; safflower ( Carthamus Tinctorius ) oil; salmon oil Sandalwood ( Santalum Album seed oil; Seabuchthorn ( Hippophae Rhamnoides ) oil; Sesame ( Sesamum Indicum ) oil; Shark liver oil; Shea butter (Seah butter) Shea Butter ( Butyrospermum Parkii ); Silkworm lipids; Skin Lipids; Soybean ( Glycine Soja ) milk; Soybean lipids; Spinolipids ; Sunflowers (Helianthus) Helianthus Annuus seed oil; sweet almond (Prunus ami) Prunus Amygdalus Dulcis ) Oil; Sweet Cherry ( Prunus Avium ) Pit Oil; Tali Oil; Tallow ; Tea Tree ( Maleuca Alternifolia) )) Oil; Telphairia Pedata Oil; Tomato ( Solanum Lycopersicum ) Oil; Triarachidine ; Tribehenin ; Tricaprine ; Tricapryline ; Trichodesma First Trichodesma Zeylanicum oil; Trierucin ; Triheptanoin; Triheptyl undecanoine; Trihydroxymethoxystearin; Trihydroxystearin; Triisononanoin; Triisopalmitin; Triisostearin; Trilaurin; Trilinoleine; Trilinolenin; Trimiristin; Trioctanoin; Triolein; Tripalmitin; Tripalmitolein; Triricinolone; Tricevacin; Tristearin; Trioundecanoin; Tuna oil; Vegetable oils; Walnut ( Juglans Regia ) oil; Bran lipids; And cotton (Triticum Vulgare) endosperm.
[81] The amount of gelling agent used to prepare the gelled ester composition, gelled ether composition, gelled alcohol composition, or gelled natural fat and oil composition will vary depending on the desired properties of the resulting gelled component but from about 0.2 to about 80 It may range from weight percent. Preferably, the gelling agent is present in about 1 to about 40 weight percent of the gelled ester composition, gelled ether composition, gelled alcohol composition, or gelled natural fat and oil composition. More preferably, the gelling agent is present at about 5 to about 20 weight percent in the gelled ester composition, gelled ether composition, gelled alcohol composition, or gelled natural fat and oil composition. In embodiments in which both diblock copolymers and triblock copolymers are used, the triblock copolymer can range from about 0.1 to about 10 weight percent, and the diblock copolymer can range from about 1 to about 40 weight percent.
[82] Gelled ester compositions, gelled ether compositions, gelled alcohol compositions, and gelled natural fats and oil compositions may optionally include one or more additional ingredients. The additional ingredient may be a suspension ingredient and / or an active ingredient.
[83] Examples of suitable solids that may be suspended in gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions include zinc oxide, coated zinc oxide, surface treated zinc oxide, titanium dioxide, Coated titanium dioxide, surface treated titanium dioxide, phosphors, fluorescent materials, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, graphite, explosives, pesticides, herbicides, fungicides, pesticides, plasticizers, air-sensitive chemicals Substances, moisture-sensitive chemicals, boron nitride, iron oxides, talc, mica, plastics, polymers, silica, silicon dioxide, aluminum oxide, organic substances, inorganic substances, organometallic substances, metal particles, medical substances (e.g. antibacterial agents) , Antibiotics, antimicrobials, antifungal and anesthetic agents), glass, clay, rubber, capsules containing the active ingredient, starch, modified starch, fragrances, coloring pigments, sunscreen active particles, varnishes, Other encapsulated material, and include, but the combination thereof is not limited to these.
[84] Examples of suitable oil insoluble liquids that can be suspended in gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions are water, water containing one or more water soluble substances, glycerin, propylene glycol, butylene Glycols, alcohols, acids, surfactants, emulsifiers, polyglycerols, ethers, polar esters, fluorinated compounds, perfluoropolyethers, silicones, silicone-containing compounds, and combinations thereof, including but not limited to these.
[85] Examples of suitable oil insoluble gases that can be suspended in gelled esters, gelled ethers, gelled alcohols, and gelled natural fats and oil compositions include hydrogen, chlorine, air, nitrogen, oxygen, carbon dioxide, propane, neon, helium, And combinations thereof, but is not limited thereto.
[86] The second component used to form the two-phase gel composition is a hydrocarbon based solvent. Preferably, suitable solvents should be hydrophobic and nonpolar. The solvent is generally water insoluble and relatively low in viscosity and substantially free of polymers. The choice of solvent for use in the two-phase composition depends on several factors, such as the desired properties of the two-phase gel composition, such as the viscosity, the desired properties of the final product into which the two-phase gel composition can be incorporated, such as the viscosity. Depends on the processing temperature, mixing capacity, suitability of the raw materials, and the like.
[87] Suitable solvents for use in the two-phase gel composition include, but are not limited to, all compounds as long as they are hydrophobic and nonpolar. Examples of suitable solvents for use in two-phase gel compositions include oils, mineral white oils, solvents, base oils, industrial mineral oils, synthetic hydrocarbons, solid hydrocarbons, semisolid hydrocarbons, waxes, petroleum distillation Substances, petrolatum, and combinations thereof, including but not limited to. In some embodiments, the solvent may be paraffin oil or naphthene oil. The solvent for use in the two-phase gel composition may be in the form of a semisolid or solid, but in the form of a liquid is preferred for ease of handling.
[88] Suitable examples of commercially available hydrophobic nonpolar solvents include Excel ^R 260 available from Excel Paralubes; Isopar ^R L, Isopar ^R M and Isopar ^R V available from Exxon Chemical; Drakeol ^R 7, Drakeol ^R 31, Drakeol ^R 34, pure white petrolatum and amber petrolatum available from Penreco; Conosol ^R C145, Conosol ^R 200, Conosol ^R 260 and Conosol ^R 340 available from Conoco, Inc .; Permethyl ^R 99A, Permethyl ^R 101A, Permethyl ^R 102A available from Presperse; And Panalane ^R 99A from Amoco.
[89] The amount of hydrophobic nonpolar solvent for use in a two-phase gel composition can be determined by several factors, such as the desired properties of the two-phase gel composition, such as viscosity, the desired properties of the final product into which the two-phase gel composition can be incorporated, Such as viscosity, processing temperature, mixing capacity, and the like. In some embodiments, the amount of solvent component present in the two-phase gel composition may range from about 5 to about 95 weight percent of the two-phase gel composition. In certain other embodiments, the solvent component is present in an amount from about 40 to about 95 weight percent of the two-phase gel composition. In another embodiment, the solvent component is present in an amount of about 60 to about 90 weight percent of the two-phase gel composition. In another embodiment, the solvent component is present in an amount from about 60 to about 80 weight percent of the two-phase gel composition.
[90] Gelled ester compositions, gelled ether compositions, gelled alcohol compositions, and gelled natural fats and oil compositions used to prepare two-phase gel compositions are described in US application Ser. No. 09 / 419,571, filed Oct. 18, 1999. Obtainable by the disclosed method, which is incorporated herein by reference. First, at least one ester, ether, alcohol, or natural fat and oil compound to be gelled is mixed with the gelling agent. Second, other temperatures are also acceptable, but typically the mixture is heated to a temperature in the range of about 70 to about 140 ° C. The mixture is stirred until a homogeneous mixture is obtained. This homogeneous mixture is cooled to room temperature to form a gelled ester composition, gelled ether composition, gelled alcohol composition, or gelled natural fat and oil composition. The compound to be gelled need not be mixed with the gelling agent before heating. Instead, the compound may first be heated to the desired temperature and then a gelling agent may be added to this compound.
[91] Two-phase gel compositions can be obtained by various methods. The process for preparing the two-phase gel composition disclosed herein is advantageous in that it requires a slight elevated temperature and generally a short mixing time. The two-phase gel composition obtained by the method described herein comprises a first component (ie, gelled ester composition, gelled ether composition, gelled alcohol composition, gelled fat and oil composition, or combinations thereof), It has a viscosity greater than or equal to the sum of the two components (solvent) and the first and second components. In some embodiments, the two-phase gel composition obtained by the method described herein has a viscosity greater than or equal to the first component, the second component, and / or the first and second components combined. In another embodiment, the two-phase gel composition obtained by the method described herein has a viscosity substantially greater than the sum of the viscosity of each component.
[92] According to an embodiment of the present invention, the two-phase gel composition can be obtained by the following method. First, one or more of gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil compositions are mixed with one or more hydrophobic nonpolar solvents to form a mixture. Second, other temperatures are also acceptable, but typically the mixture is heated to a temperature in the range of about 40 to about 60 ° C. The mixture is stirred until a homogeneous mixture is obtained. This homogeneous mixture is cooled to room temperature. This gives a two-phase gel composition.
[93] According to another embodiment, the two-phase gel composition can be obtained by the following method. First, one or more gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil compositions are heated to temperatures in the range of about 40 to about 60 ° C., although other temperatures are also acceptable. Second, the heated gelled component is mixed with one or more hydrophobic nonpolar solvents. The mixture is stirred until a homogeneous mixture is obtained. This homogeneous mixture is cooled to room temperature. This gives a two-phase gel composition.
[94] According to other embodiments, the two-phase gel composition can be obtained by the following method. First, one or more hydrophobic non-polar solvents are heated to temperatures in the range of about 40 to about 60 degrees Celsius, although other temperatures are also acceptable. Second, the heated solvent is mixed with one or more gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil compositions to form a mixture. The mixture is stirred until a homogeneous mixture is obtained. This homogeneous mixture is cooled to room temperature. This gives a two-phase gel composition.
[95] According to another embodiment, the two-phase gel composition can be obtained by the following method. First, one or more hydrophobic non-polar solvents are heated to temperatures in the range of about 40 to about 60 degrees Celsius, although other temperatures are also acceptable. Separately, one or more gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil compositions are also heated to temperatures in the range of about 40 to about 60 ° C. although other temperatures are also acceptable. Second, the heated solvent is mixed with the heated gelled components to form a mixture. The mixture is stirred until a homogeneous mixture is obtained. This homogeneous mixture is cooled to room temperature. This gives a two-phase gel composition.
[96] In another aspect, the two-phase gel composition can be obtained by the following method. The method includes mixing one or more gelled esters, gelled ethers, gelled alcohols, or gelled natural fats and oil compositions with one or more hydrophobic nonpolar solvents at room temperature to form a two-phase gel composition. In some embodiments, the two-phase gel composition obtained by this method can be used for spill control.
[97] The following examples are provided to illustrate embodiments of the invention. These are merely examples and are not intended to limit the scope of the invention other than as described herein. All values described herein are approximate. In some embodiments, antioxidant is added in an amount of about 0.02%. In another embodiment, antioxidant is added in an amount of about 0.05 to about 0.20%. Any antioxidant can be used. Suitable antioxidants are 2,6-di-tert-butyl-4-methylphenol ("BHT").
[98] Example 1
[99] Gelled isopropyl myristate samples were prepared (trade name Estol ^R IPM 1512 (available from Unichema) and Lexol ^R IPM (available from Inolex)) (85.28 wt% isopropyl Myristate + 14.30 wt% Kraton ^R G1702 + 0.40 wt% Kraton ^R G1650). The finished gel showed good transparency and had a Brookfield viscosity (5 rpm, spindle TC) of 157,000 cPs at 25 ° C.
[100] Example 2
[101] Gelled octyl methoxycinnamate samples (trade name Parsol ^R MCX (available from Givaudan-Roure), Escalol ^R 557 (available from ISP Van Dyk) and Neo Heliopan ^R AV (available from Haarman & Reimer) was prepared (87.58 wt% octyl methoxycinnamate + 12.00 wt% Kraton ^R G1701 + 0.40 wt% Kraton ^R G1650). The finished gel was clear and stable over several freeze / thaw cycles.
[102] Example 3
[103] Samples of zinc oxide suspension in gelled octyl methoxycinnamate were prepared using 50.00 wt% zinc oxide and 50.00 wt% gelled octyl methoxycinnamate described in Example 2. The finished suspension was excellent in consistency and remained stable without separation under thermal stress for 15 days.
[104] Example 4
[105] A gelled propylene glycol dicaprylate / caprate sample (trade name Estol ^R PDCC 1526 (available from Unichema)) was prepared (87.58 wt% propylene glycol dicaprylate / caprate + 12.00 wt% Kraton ^R G1780 + 0.40 wt % Kraton ^R G1650). This gel was clear at ambient temperature.
[106] Example 5
[107] A gelled isostearyl neopentanoate sample (trade name Dermol ^R 185, available from Bernel) was prepared (85.58 wt% isostearyl neopentanoate + 14.00 wt% Septon ^R 1001 + 0.40 wt% Kraton ^R G1650). The finished gel was clear and stable without census.
[108] Example 6
[109] Jojoba oil gels were prepared (91.28 wt% jojoba oil + 0.4 wt% Kraton ^R G1650 + 8.3 wt% Kraton ^R G1702). The finished gel was clear and viscous.
[110] Example 7
[111] Ecosyl erucate (trade name Erucical ^R EG-20 (available from Lambent) was prepared (91.28 wt% Erucical ^R EG-20 + 0.4 wt% Kraton ^R G1650 + 8.3 wt% Kraton ^R G1702). The finished gel was clear and stable without cinesyses.
[112] In addition to the above examples of gel compositions, many other compositions were also obtained. Tables 3 to 6 summarize the gel compositions obtained according to embodiments of the invention.
[113] TABLE 3
[114]
[115] Table 4
[116]
[117] Table 5
[118]
[119] Table 6
[120]
[121] Example 8
[122] Gelled soybean oil samples (available under the Alkai Refined Soybean Oil from Cargill) were prepared (85.90 wt% soybean oil + 14.00 wt% Kraton ^R D1102). The finished gel showed good transparency and had a Brookfield viscosity (2.5 rpm, spindle TC) of 18,000 cPs at 22 ° C. The gel was clear and stable after testing for 4 weeks of accelerated aging at 50 ° C. and 3 freeze / thaw cycles (-20-25 ° C.) in an oven. This gelled soybean oil was mixed with the hydrocarbon solvent Conosol ^R 340 at a weight ratio as shown in Table 7 at 40 to 45 ° C. for 15 to 20 minutes to prepare five two-phase gel compositions (two-phase gel compositions 1 to 5). Formed.
[123] TABLE 7
[124] ingredientTwo-Phase Gel Compositions 1Two-Phase Gel Compositions 2Two-Phase Gel Compositions 3Two-Phase Gel Compositions 4Two-Phase Gel Compositions 5 Gelled Soybean Oil (wt%)2030405070 Conosol ^R 340 (wt%)8070605030
[125] Table 8 provides information on the physical properties of Conosol ^R available from Conoco, Inc.
[126] Table 8
[127] characteristicNormalized valueTypical valueTest Methods API gravity, 15.6 ° C (60 ° F)31.0-34.032ASTM D-287 Specific gravity, 15.6 ° C (60 ° F) 0.8654Theoretical method Pounds per gallon (PPG), 15.6 ° C (60 ° F) 7.22Theoretical method Refractive Index, 20 ° C (68 ° F) 1.4714ASTM-D1218 Flash Point (Enclosed Container Technique), ℃ (℉)171 (340) minimum177 (350)ASTM D-93 Pour point, ° C (℉) -45 (-50)ASTM D-97 Kauri-butanol No. 22.4ASTM D-1133 Aniline point, ℃ (℉) 90 (195)ASTM D-611 Color (say bolt) +27ASTM D-156 Sulfur (PPM) <1ASTM D-4045 Composition (Wt%) SFC, pen-join method Saturation > 99.5Aromatic <0.5Viscosity @ 40C, cSt (SUS) 10.2 (59.5)ASTM D-445 Distillation range ASTM D-86
[128] ℃℉standard I.B.P.327620316 (600) minimum 5%33263010%33263050%33563590%34064595%342648E.P.349660360 (680) max
[129] 1 is a graph of viscosity versus gelled soybean oil concentration for two-phase gel compositions 1-5. The concentrations of the gelled soybean oil components and the Brookfield viscosity (2.5 rpm, spindle T-C at 22 ° C.) measurements are shown in Table 9.
[130] Table 9
[131] Gelled Soybean Oil Concentration (wt%)Viscosity (cPs) 20200,000 30288,000 40180,000 5040,000 7017,000 10018,000
[132] The two-phase gel compositions 1 to 5 were clear and showed good thermal stability even after two weeks and three freeze / thaw cycles at 50 ° C. in an oven.
[133] Example 9
[134] Gelled soybean oil samples (available under the trade name Alkai Refined Soybean Oil from Cargill) were prepared (85.90 wt% soybean oil + 14.00 wt% Kraton ^R D1102). The finished gel showed good transparency and had a Brookfield viscosity (50 rpm, spindle TC) of 18,000 cPs at 22 ° C. The gel was clear and still clear and stable after testing for 4 weeks of accelerated aging at 50 ° C. and 3 freeze / thaw cycles (-20-25 ° C.) in an oven.
[135] This gelled soybean oil was mixed with a low sulfur diesel fuel available from Amoco, a hydrocarbon solvent, at a weight ratio as shown in Table 10 for 15 to 20 minutes at room temperature to form three two-phase gel compositions (two-phase gel composition). 6 to 8).
[136] Table 10
[137] ingredientTwo-Phase Gel Compositions 6Two-Phase Gel Compositions 7Two-Phase Gel Compositions 8 Gelled Soybean Oil (wt%)90%80%65% Diesel fuel (wt%)10%20%35%
[138] 2 is a graph of viscosity versus diesel fuel concentration for two-phase gel compositions 6-8. The concentrations and Brookfield viscosity (at 50 rpm, spindle T-C, 22 ° C.) measurements of the diesel fuel composition are shown in Table 11.
[139] Table 11
[140] Diesel fuel concentration (wt%)Viscosity (cPs) 10700 20120 350
[141] Two-phase gel compositions 6-8 were stable for 3 months at room temperature.
[142] Example 10
[143] Gelled soybean oil samples (available under Alkai Refined Soybean Oil) were prepared (87.80 wt% soybean oil + 12.00 wt% Kraton ^R D1160). The finished gel showed good transparency and had a Brookfield viscosity (2.5 rpm, spindle TC) of 5,000 cPs at 22 ° C.
[144] This gelled soybean oil was mixed with mineral oil (available under the tradename Excel ^R 260) (35 wt% gelled soybean oil + 65 wt% Excel ^R 260 oil) to form a two-phase gel composition.
[145] Table 12
[146] Appearance: transparent and clear Odor: HydrocarbonVapor Pressure: <1 mmHg @ 392F Physical state: Inaccessible informationVapor Density (Air = 1)> 1 pH: no data availablePercent Volatile to Volume: No Data Available Boiling Point: Not ApplicableVolatile Organic Content: No data available Melting Point: InapplicableMolecular Weight:> 350 Specific gravity: 0.87Average carbon number: no data available Pour point: 5 ° F, -15 ° CViscosity @ 100F: 259 SUSViscosity @ 40C: 50.1 cSt Solubility in water: water insoluble Octanol / water coefficient: Log K _ow = data not available
[147] The two-phase gel composition had a Brookfield viscosity of about 1000 times (2.5 rpm, spindle T-C) than the original gelled soybean oil. This two-phase gel composition showed good thermal stability and transparency.
[148] Example 11
[149] Gelled isopropyl myristate samples (available under the tradename isopropyl myristate from Spectrum) were prepared (74.95 wt% isopropyl myristate + 25.00 wt% Kraton ^R D1102). The finished gel was opaque and had a Brookfield viscosity of 5800 cPs (5 rpm, spindle TC) at 25 ° C.
[150] This gelled isopropyl myristate was mixed with Conosol ^R 340 (13 wt% gelled isopropyl myristate + 87 wt% Conosol ^R 340) to form a two-phase gel composition. This two-phase gel composition had a Brookfield viscosity (2.5 rpm, spindle TC) approximately 100 times greater than the original gelled isopropyl myristate. This two-phase gel composition was cloudy at room temperature and had limited stability.
[151] Example 12
[152] Gelled isopropyl myristate samples (available under the tradename isopropyl myristate from Spectrum) were prepared (85.95 wt% isopropyl myristate + 14.00 wt% Kraton ^R G1650). The finished gel showed colorless transparent transparency and good stability and had a Brookfield viscosity (2.5 rpm, spindle TC) of 3600 at 25 ° C.
[153] This gelled isopropyl myristate was mixed with Drakeol ^R 7 at 50 ° C. for 15 minutes (30 wt% gelled isopropyl myristate + 70 wt% Drakeol ^R 7) to form a two-phase gel composition. Table 13 provides information on the physical properties of Drakeol ^R 7 available from Penreco.
[154] Table 13
[155] Mineral oilTypical valueTypical characteristics ViscosityAPIimportanceflash pointPour point ASTM D 445ASTM D 1298ASTM D 92ASTM D 97SUS @ 100 ℉CST @ 40 ℃@ 60 ℉@ 60 ℉@ 77 ℉℉℃℉℃ Drakeol ^R 765/7510.8 / 13.634.4 / 38.5.832 / .853.826 / .84735017715-9
[156] This two-phase gel composition showed good transparency and thermal stability and had a Brookfield viscosity (2.5 rpm, spindle T-C) at 25 ° C. of 219,000 cPs.
[157] Example 13
[158] Gelled isopropyl myristate samples (available under the tradename isopropyl myristate from Spectrum) were prepared (73.95 wt% isopropyl myristate + 26.00 wt% Kraton ^R G1650). The finished gel showed colorless transparent transparency and good stability and had a Brookfield viscosity (5 rpm, spindle TC) of 117,000 cPs at 25 ° C.
[159] This gelled isopropyl myristate was mixed with Excel ^R 260 and Isopar ^R M (28 wt% gelled isopropyl myristate, 36 wt% Excel ^R 260 and 36 wt% Isopar ^R M) to prepare a two-phase gel composition. Formed. Table 14 provides information on the physical properties of Isopar ^R M available from Exxon Chemical.
[160] Table 14
[161] GradeM Soluble kauri-butanol value aniline point, ° C2591 (196) Volatile flash point, TCC ℃ (℉) distillation, ℃ (℉) IBP drying point93 (199) 223 (433) 254 (489) Gravity Specific Gravity @ 15.6 (60 ℉)0.79 Composition, mass% Saturation degree Aromatic99.9 <0.05 Purity, ppm Acid Chloride Nitrogen Peroxide SulfurNothing-<1 <2 Surface Tension, Dyne / cm @ 25 ° C (77 ° F) Surface Tension @ 25 ° C (77 ° F)26.452.2 EmulsifyingGreat
[162] The two-phase gel composition had a Brookfield viscosity (5 rpm, spindle T-C) approximately 1000 times greater than the original gelled isopropyl myristate.
[163] Example 14
[164] Gelled isopropyl myristate samples (available under the tradename isopropyl myristate from Spectrum) were prepared (79.95 wt% isopropyl myristate + 20.00 wt% Kraton ^R G1650). The finished gel showed colorless transparency and good stability and had a Brookfield viscosity of 12,000 cPs (1 rpm, spindle TC) at 25 ° C.
[165] This gelled isopropyl myristate was mixed with Excel ^R 260 in the weight ratios shown in Table 15 below to prepare six two-phase gel compositions (two-phase gel compositions 9-14).
[166] Table 15
[167] ingredientTwo-Phase Gel Compositions 9Two-Phase Gel Compositions 10Two-Phase Gel Compositions 11Two-Phase Gel Compositions 12Two-Phase Gel Compositions 13Two-Phase Gel Compositions 14 Gelated Isopropyl Myristate (wt%)102030405070 Excel ^R 260 (wt%)908070605030
[168] 3 is a graph of viscosity versus gelled isopropyl myristate concentration for two-phase gel compositions 9-14. The concentration of the gelled isopropyl myristate and the Brookfield viscosity (at 1 rpm, spindle T-C, 22 ° C.) measurements are shown in Table 16.
[169] Table 16
[170] Gelled Isopropyl Myristate Concentration (wt%)Viscosity (cPs) 1088,000 20900,000 302,000,000 402,000,000 50286,000 7012,000
[171] The two-phase gel compositions 9-14 were clear and showed good thermal stability even after two weeks and three freeze / thaw cycles at 50 ° C. in an oven.
[172] Example 15
[173] A gelled mixture of C12-15 alkyl benzoate (available under Fintex from Finsolv ^R ) and Kraton ^R D1102 was prepared. C12-15 alkyl benzoate was mixed (42.9 wt%) with peanut oil (42.9 wt%) and heated to 70-75 ° C. Kraton ^R D1102 was then added to form a gelled mixture. The finished gelled mixture was pale yellow with good transparency and thermal stability.
[174] The gelled mixture was mixed with Conosol ^R 260 (70 wt% gelled mixture and 30 wt% Conosol ^R 260) to form a two-phase gel composition. This two-phase gel composition showed good transparency and viscosity and had a Brookfield viscosity (5 rpm, spindle TC) of 5000 cPs at 25 ° C. Table 17 provides information on the physical properties of Conosol ^R 260 available from Conoco, Inc.
[175] Table 17
[176] characteristicNormalized valueTypical valueTest Methods API gravity, 15.6 ° C (60 ° F)37.0-40.038.5ASTM D-287 Specific gravity, 15.6 ° C (60 ° F) 0.8324Theoretical method Pounds per gallon (PPG), 15.6 ° C (60 ° F) 6.94Theoretical method Refractive Index, 20 ° C (68 ° F) 1.4571ASTM-D1218 Flash Point (Enclosed Container Technique), ℃ (℉)116 (240) minimum121 (250)ASTM D-93 Pour point, ° C (℉) -51 (-60)ASTM D-97 Kauri-butanol No. 23.8ASTM D-1133 Aniline point, ℃ (℉) 86 (187)ASTM D-611 Color (say bolt) +30ASTM D-156 Sulfur (PPM) <1ASTM D-4045 Composition (Wt%) SFC, pen-join method Saturation > 99.5Aromatic <0.5Viscosity @ 40C, cSt (SUS) 4.3 (40.2)ASTM D-445 Distillation range ASTM D-86
[177] ℃℉standard I.B.P.271520260 (500) 5%28053610%28153750%29155590%30958995%313596E.P.324615329 (625) max
[178] Two-phase gel compositions according to embodiments of the invention have a number of cosmetic, health and beauty, home care and industrial uses. Two-phase gel compositions may be used alone or in combination with one or more additional ingredients. The amount of additional components used in the two-phase gel composition depends on the desired properties of the final product in which the two-phase gel composition can be used. For example, two-phase gel compositions may include lubricants, suspending agents, emulsifying stabilizers, thickening agents, individual care ingredients, air fresheners, pesticide and pesticide ingredients, candles and decorative products, pharmaceutical carriers and carrier ingredients, It is suitable as an ointment base ingredient, sporting goods ingredient, cleaning ingredient ingredient, explosive material and explosive emulsion ingredient, spill control agent, drilling mud ingredient, well finish material, and other materials transporting vehicle. Since esters are generally biodegradable, gelled esters can be applied to products that require minimal contamination. Examples include fishing line lubricants, solder fluxes, agricultural dust reducers and lubricants, textile coatings, protective coatings for transporting fragile or environmentally sensitive materials, and biodegradable oils and greases.
[179] It has been found that a two-phase gel composition according to an embodiment of the invention keeps the solids, liquids and / or gases suspended or evenly dispersed substantially uniformly for a substantial period of time. The suspended solids, liquids and / or gases may be present in the two-phase gel composition in an amount of up to 95% by weight. Suitable solids, liquids and / or gases that may be suspended in the two-phase gel composition include any solid, non-hydrocarbon liquid or gas that will be dispersed into the gel and substantially suspended or evenly dispersed therein.
[180] Examples of suitable solids that may be suspended in two-phase gel compositions include zinc oxide, coated zinc oxide, surface-treated zinc oxide, titanium dioxide, coated titanium dioxide, surface-treated titanium dioxide, phosphors, fluorescent Substances, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, graphite, explosives, pesticides, herbicides, fungicides, pesticides, plasticizers, air-sensitive chemicals, moisture-sensitive chemicals, boron nitride, iron oxides, talc , Mica, plastics, polymers, silica, silicon dioxide, aluminum oxide, organic materials, inorganic materials, organometallic materials, metal particles, medical materials (such as antibacterial agents, antibiotics, antimicrobial agents, antifungal and anesthetic agents), glass, clay, rubber Capsules containing the active ingredient, starches, modified starches, fragrances, coloring pigments, sunscreen active particles, varnishes, other encapsulated materials, and combinations thereof. Do not.
[181] Examples of oil-insoluble liquids that may be suspended in two-phase gel compositions include water, water containing one or more water soluble substances, glycerin, propylene glycol, butylene glycol, alcohols, acids, surfactants, emulsifiers, polyglycerols, ethers , Polar esters, fluorinated compounds, perfluoropolyethers, silicones, silicone-containing compounds, and combinations thereof, including, but not limited to.
[182] Examples of oil-insoluble gases that may be suspended in two-phase gel compositions include, but are not limited to, hydrogen, chlorine, air, nitrogen, oxygen, carbon dioxide, propane, neon, helium, and combinations thereof.
[183] Pending U.S. Patent Application No. 09 / 007,838, filed Jan. 15, 1998, entitled “Hydrocarbon Gels and Products as Suspending and Dispersing Agents”, discloses a process for preparing suspension systems based on gelled hydrocarbons. have. The disclosed methods can be used in embodiments of the present invention to make suspension systems based on gelled esters, gelled alcohols, or gelled natural fats and oils. The disclosures of the above-cited patent applications are all incorporated herein by reference.
[184] Two-phase gel compositions according to embodiments of the invention also have a wide range of cosmetic and health and cosmetic uses when the gel composition comprises an effective amount of one or more cosmetic and health and beauty supplement components. "Effective amount" means that a sufficient amount of ingredients are present in the composition to achieve the desired purpose. An effective amount can be set in the range of about 0.001 to about 95 wt%. "Cosmetics and health and beauty supplements" means cleaning, beautifying, promoting attractiveness, and protecting skin conditions without altering or impairing the physiological capabilities of human skin or body; Any substance that can be applied topically to human skin or any part thereof for improvement. Included within this definition are creams, lotions, emollients, fragrance oils, massage oils, humectants, humectants, cosmetic oils and the like. Two-phase gel compositions according to embodiments of the invention may also contain skin care preservatives, diluents, surfactants, anti-wrinkle agents and the like.
[185] In addition, two-phase gel compositions can be used to make over-the-counter ("OTC") products. The OTC product can be made entirely from the gel composition or only one component of the OTC is made from the gel composition. Examples of OTC products include limiters, lip balms, and sunscreens (for example, natural sunblocks such as metal oxides of submicron particles or synthetic sunblocks such as octylmethoxycinnamate and benzophenone-3) But not limited to these.
[186] As mentioned above, the two-phase gel composition according to the embodiment of the present invention can be used as a carrier vehicle for topical administration of various cosmetic and health and beauty aids to the skin. Thus, these substances are incorporated into gels that are applied to and absorbed by the skin to form a film on the skin to give a cool feeling, to treat dry or oily skin, to feed the substance into the skin, to improve the overall skin texture or to color Can be improved. All of these effects have been attempted to be achieved by various health and beauty supplement products. Methods of making such skin care products are known in the art. For example, US Pat. No. 5,558,872 discloses a clear skin protectant based on gelled mineral oil. Similar skin protectants can be prepared by substituting the gelling composition according to an embodiment of the invention in place of a mineral oil gel. The disclosures of US Pat. No. 5,558,872 are all incorporated herein by reference.
[187] Preferred use of the two-phase gel composition according to an embodiment of the present invention involves the formation of concentrated liquids, soft gels and semisolid gels. Gels are particularly useful for water resistant sunscreen compositions, makeup, mascara and the like. They are also useful for petrolatum-based products such as petrolatum jelly, makeup foundations and night creams. They can also be used as substitutes for water soluble polymers in products such as lip balm-creams, eyeliner liquids and the like. They can also be used as gelling agents in facial oils.
[188] Semi-solid or solid gels are intended for use as stick-type cosmetics such as stick-type insect repellents, or for transparent or opaque stick-type products containing deodorants, limiting agents, lipsticks, analgesics, scouring papers, solid lotions and solid absorbent flowable gels. It has a use as a matrix. For example, US Pat. No. 5,756,082 discloses a stick cosmetic composition based on a hydrocarbon oil gel. Stick-type cosmetic compositions can be prepared by substituting the above-described hydrocarbon oil gel with a gel composition according to an embodiment of the present invention. The disclosures of US Pat. No. 5,756,082 are all incorporated herein by reference.
[189] Two-phase gel compositions according to embodiments of the invention also have a wide range of home care uses when the gel composition comprises an effective amount of one or more home care ingredients. "Effective amount" means that a sufficient amount of ingredients are present in the composition to achieve the desired purpose. The effective amount may range from about 0.001 to about 95 wt%. "Home care ingredients" may include, but are not limited to, any materials that can be incorporated, mixed and / or added to cleaning, improving and beautifying hydrocarbon products, such as homes. "Home care ingredients" may also include, but are not limited to, any materials that can be used to protect and / or modify the surface appearance, ie by polishing or cleaning. Examples of home care applications include, but are not limited to, candles, air fresheners, aerosols, pesticides, herbicides, fungicides, plasticizers, insecticides, cleaning products, gloss products, and the like.
[190] Two-phase gel compositions according to embodiments of the invention also have a wide range of industrial uses when the gel composition comprises an effective amount of one or more industrial components. For example, two-phase gel compositions according to embodiments of the present invention can be used as carrier vehicles for industrial particulate suspensions. Industrial uses can include a variety of industrial uses, both large and small. Examples of industrial uses include drilling mud and other fluids such as crude oil; Drilling, forming, finishing and treating underground formations such as wells; detergent; Explosive substances; Explosive emulsions; Paint and coating applicators; Spill regulators; Printing inks, solder products; And the like, but are not limited to these. "Effective amount" means that a sufficient amount of ingredients are present in the composition to achieve the desired purpose. The effective amount may range from about 0.001 to about 95 wt%.
[191] As demonstrated above, two-phase gel compositions according to embodiments of the invention have a wide range of industrial, cosmetic, health and beauty, and home care uses. When used as such, the two-phase gel composition may exhibit one or more of the following properties or advantages: transparency, compatibility with the active ingredient, reduction and removal of syneresis, stable of ingredients such as organic or inorganic materials Function as a vehicle to provide suspension; Moisturizing; Reduction of skin irritation; Water resistance improvement; Improved provision of SPF when formulated into sunscreen products; Absorption and irritation reduction; liquidity; Fluidity control ability; Solubility; Wettability; Whitening effect elimination and minimization; Function as a moisturizing membrane; Function as a cosmetic base; Sustained release of volatile or active ingredients; Self-emulsifying; and formation with small amounts of emulsifiers. Other features and advantages are apparent to those skilled in the art.
[192] Although the present invention has been described with respect to a limited number of embodiments, there are variations and modifications therefrom. For example, although suitable esters, ethers, alcohols and natural fats and oils are described in some depth, other compounds may also be used to form the gelled components. Further suitable esters may include alkoxylated fatty acids, glyceryl ethers and sorbitan derivatives. Further suitable alcohols may include alkanolamides, alkanolamines, fatty alcohols, polyols, phenols and sterols. Further suitable ethers include heterocyclic ethers such as tocopherols, alkoxylated alcohols, alkoxylated amides, alkoxylated amines, alkoxylated carboxylic acids, polymer ethers and glyceryl ethers. Similarly, natural fats and oils may include so-called "essential oils" which are volatile organic components of plants usually obtained by distillation. In addition to the compounds described above, aldehydes and ketones may also be formed into gel compositions according to embodiments of the invention. In addition, although two-phase gel compositions have been described that are prepared from gelled esters, gelled ethers, gelled alcohols, gelled natural fats and oils, or combinations thereof, and hydrophobic nonpolar solvents, other compounds may be used. For example, gelled aldehydes and gelled ketones may also be used to form the two-phase gel composition. It is intended that the appended claims cover all such variations and modifications as fall within the scope of the present invention.

权利要求:
Claims (49)
[1" claim-type="Currently amended] Gelled ester composition having a viscosity η ₁ , containing a mixture of ester compounds and polymer compounds selected from the group consisting of triblock copolymers, star polymers, radial polymers, multiblock copolymers, and combinations thereof And
Contains a hydrophobic nonpolar solvent having a viscosity η ₂ ,
A two-phase gel composition substantially free of phosphate compounds and having a viscosity η greater than or equal to η _{1 and} greater than or equal to η ₂ .
[2" claim-type="Currently amended] 2. The _two -phase gel composition of claim ₁ , having a viscosity substantially greater than or equal to the sum of η ₁ and η ₂ .
[3" claim-type="Currently amended] 2. The two-phase gel composition of claim 1, further comprising a diblock copolymer and wherein the gelled ester composition is substantially free of mineral oil.
[4" claim-type="Currently amended] The two-phase gel composition of claim 1, wherein the ester compound is represented by the following general formula:
And
Where
n = 1, 2, 3 and 4;
R ₁ comprises hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl or substituted phenyl;
R ₂ comprises hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl, substituted phenyl, alkylene, phenylene, substituted alkylene or substituted phenylene.
[5" claim-type="Currently amended] The two-phase gel composition of claim 1, wherein the ester compound is represented by the general formula:

Where
R ₁ comprises hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl or substituted phenyl;
R ₃ comprises alkylene, phenylene, substituted alkylene or substituted phenylene.
[6" claim-type="Currently amended] The two-phase gel composition of claim 1, wherein the ester compound is represented by the general formula:

Where
R ₄ , R ₅ and R ₆ individually comprise alkylene, phenylene, substituted alkylene or substituted phenylene,
R ₇ , R ₈ and R ₉ individually include hydrogen, hydrocarbyl, phenyl, methoxyphenyl, alkylphenyl, substituted alkyl or substituted phenyl.
[7" claim-type="Currently amended] The method of claim 1, wherein the ester compound is isopropyl myristate, isopropyl palmitate, C _12-15 alkyl benzoate, octyl methoxycinnamate, octyl dodecyl neopentanoate, propylene glycol dicaprylate / caprate, A gel composition selected from the group consisting of jojoba oil and isostearyl neopentanoate.
[8" claim-type="Currently amended] 4. The gel composition of claim 3, wherein the diblock copolymer is selected from the group consisting of styrene-ethylene / propylene copolymers, styrene-ethylene / butadiene copolymers, styrene-isoprene copolymers, styrene-butadiene copolymers, and mixtures thereof.
[9" claim-type="Currently amended] The method of claim 1, wherein the triblock copolymer is a styrene-ethylene / propylene-styrene copolymer, a styrene-ethylene / butadiene-styrene copolymer, a styrene-isoprene-styrene copolymer, a styrene-butadiene-styrene copolymer and mixtures thereof Gel composition selected from the group consisting of.
[10" claim-type="Currently amended] The gel of claim 1 wherein the solvent is selected from the group consisting of oils, mineral white oils, base oils, industrial mineral oils, synthetic hydrocarbons, solid hydrocarbons, waxes, petroleum distillates and combinations thereof. Composition.
[11" claim-type="Currently amended] The gel composition of claim 1, wherein the gelled ester composition is present in an amount from about 5 to about 95 weight percent of the two-phase gel composition.
[12" claim-type="Currently amended] The gel composition of claim 1, wherein the gelled ester composition is present in an amount from about 10 to about 40 weight percent of the two-phase gel composition.
[13" claim-type="Currently amended] The gel composition of claim 1, wherein the solvent is present in an amount from about 5 to about 95 weight percent of the two-phase gel composition.
[14" claim-type="Currently amended] The gel composition of claim 1, wherein the solvent is present in an amount from about 60% to about 90% by weight of the two-phase gel composition.
[15" claim-type="Currently amended] The gel composition of claim 1, further comprising a suspending component.
[16" claim-type="Currently amended] 16. The gel composition of claim 15, wherein the suspension component is a solid selected from the group consisting of organic materials, inorganic materials, organometallic materials, phosphors and fluorescent materials.
[17" claim-type="Currently amended] The method of claim 15, wherein the suspending component is zinc oxide, coated zinc oxide, surface-treated zinc oxide, titanium dioxide, coated titanium dioxide, surface-treated titanium dioxide, graphite, explosive materials, air-sensitive chemicals, Moisture-sensitive chemicals, boron nitride, iron oxides, talc, mica, plastics, polymers, silica, silicon dioxide, aluminum oxide, metal particles, antibacterial agents, antibiotics, anesthetics, glass, clay, rubber, capsules containing the active ingredient, starch Modified starches, fragrances, coloring pigments, sunscreen active particles, brighteners, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, pesticides, herbicides, fungicides, insecticides, plasticizers, medical substances, antimicrobial agents, antifungal agents, other A gel composition which is a solid selected from the group consisting of an encapsulated material and combinations thereof.
[18" claim-type="Currently amended] The method of claim 15 wherein the suspending component is water, water containing water-soluble substances, glycerin, propylene glycol, butylene glycol, alcohols, acids, surfactants, emulsifiers, polyglycerols, ethers, polar esters, fluorinated compounds, purple A gel composition which is a liquid selected from the group consisting of fluoropolyethers, silicones, silicone-containing compounds and combinations thereof.
[19" claim-type="Currently amended] 16. The gel composition of claim 15, wherein the suspension component is a gas selected from the group consisting of hydrogen, chlorine, air, nitrogen, oxygen, carbon dioxide, propane, neon, helium and combinations thereof.
[20" claim-type="Currently amended] The gel composition of claim 1, further comprising an active ingredient.
[21" claim-type="Currently amended] 21. The gel composition of claim 20, wherein the active ingredient is selected from sunscreens, limiters, deodorants, perfumes, cosmetics, emollients, repellents, pesticides, herbicides, fungicides, plasticizers, insecticides and pharmaceuticals.
[22" claim-type="Currently amended] Ether compounds, alcohol compounds, or mixtures of gelled natural fat and oil compositions with polymeric compounds selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers, and combinations thereof And a gelled composition having a viscosity η ₁ selected from the group consisting of a gelled ether composition, a gelled natural fat and oil composition, and combinations thereof, and
Contains a hydrophobic nonpolar solvent having a viscosity η ₂ ,
A two-phase gel composition having a viscosity η greater than or equal to η _{1 and} greater than or equal to η ₂ .
[23" claim-type="Currently amended] 23. The _two -phase gel composition of claim 22, having a viscosity substantially greater than or equal to the sum of η ₁ and η ₂ .
[24" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the alcohol comprises octyl dodecanol or isostearyl alcohol.
[25" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the ether comprises dicaprylyl ether or octyl methoxycinnamate.
[26" claim-type="Currently amended] 23. The two-phase oil according to claim 22, wherein the natural fats and oils comprise flaxseed oil, soybean oil, sunflower seed oil, corn oil, sesame oil, olive oil, castor oil, coconut oil, palm oil, peanut oil, jojoba oil and macadamia nut oil. Gel composition.
[27" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the solvent is selected from the group consisting of oils, mineral white oils, base oils, industrial mineral oils, synthetic hydrocarbons, solid hydrocarbons, waxes, petroleum distillates and combinations thereof.
[28" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the gelled composition is present in an amount from about 5 to about 95 weight percent of the two-phase gel composition.
[29" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the gelled composition is present in an amount from about 10 to about 40 weight percent of the two-phase gel composition.
[30" claim-type="Currently amended] 23. The two-phase gel composition of claim 22, wherein the solvent is present in an amount from about 5 to about 95 weight percent of the two-phase gel composition.
[31" claim-type="Currently amended] 23. The gel composition of claim 22, wherein the solvent is present in an amount from about 60 to about 90 weight percent of the two-phase gel composition.
[32" claim-type="Currently amended] 23. The gel composition of claim 22, further comprising a suspending component.
[33" claim-type="Currently amended] 33. The two-phase gel composition of claim 32, wherein the suspension component is a solid selected from the group consisting of organic materials, inorganic materials, organometallic materials, phosphors and fluorescent materials.
[34" claim-type="Currently amended] 33. The method of claim 32, wherein the suspending component comprises zinc oxide, coated zinc oxide, surface-treated zinc oxide, titanium dioxide, coated titanium dioxide, surface-treated titanium dioxide, graphite, explosives, air-sensitive chemicals, Moisture-sensitive chemicals, boron nitride, iron oxides, talc, mica, plastics, polymers, silica, silicon dioxide, aluminum oxide, metal particles, antibacterial agents, antibiotics, anesthetics, glass, clay, rubber, capsules containing the active ingredient, starch Modified starches, fragrances, coloring pigments, sunscreen active particles, brighteners, molybdenum oxide, zinc sulfide, copper-doped zinc sulfide, pesticides, herbicides, fungicides, insecticides, plasticizers, medical substances, antimicrobial agents, antifungal agents, other A two-phase gel composition which is a solid selected from the group consisting of an encapsulated material and combinations thereof.
[35" claim-type="Currently amended] 33. The composition of claim 32 wherein the suspending component is water, water containing water-soluble substances, glycerin, propylene glycol, butylene glycol, alcohols, acids, surfactants, emulsifiers, polyglycerols, ethers, polar esters, fluorinated compounds, purple A two-phase gel composition which is a liquid selected from the group consisting of fluoropolyethers, silicones, silicone-containing compounds and combinations thereof.
[36" claim-type="Currently amended] 33. The two-phase gel composition of claim 32, wherein the suspension component is a gas selected from the group consisting of hydrogen, chlorine, air, nitrogen, oxygen, carbon dioxide, propane, neon, helium, and combinations thereof.
[37" claim-type="Currently amended] The two-phase gel composition of claim 1, further comprising an active ingredient.
[38" claim-type="Currently amended] 38. The two-phase gel composition of claim 37, wherein the active ingredient is selected from sunscreens, limiters, deodorants, perfumes, cosmetics, emollients, insecticides, pesticides, herbicides, fungicides, plasticizers, insecticides and pharmaceuticals.
[39" claim-type="Currently amended] A gelled composition selected from the group consisting of gelled ester compositions, gelled ether compositions, gelled alcohol compositions, gelled natural fats and oil compositions, and combinations thereof, with a hydrophobic nonpolar solvent to form a mixture; Heating the mixture; Stirring the mixture until the mixture is homogeneous; Cooling the mixture to form a two-phase gel composition having a viscosity greater than or equal to the viscosity of the gelled composition and having a viscosity greater than or equal to the viscosity of the solvent.
[40" claim-type="Currently amended] Heating the gelled composition selected from the group consisting of gelled ester compositions, gelled ether compositions, gelled alcohol compositions, gelled natural fats and oil compositions, and combinations thereof; The heated gelled composition is mixed with a hydrophobic nonpolar solvent to form a mixture; Stirring the mixture until the mixture is homogeneous; Cooling the mixture to form a two-phase gel composition having a viscosity greater than or equal to the viscosity of the gelled composition and having a viscosity greater than or equal to the viscosity of the solvent.
[41" claim-type="Currently amended] Heating the hydrophobic nonpolar solvent; The heated solvent is mixed with a gelled composition selected from the group consisting of gelled ester compositions, gelled ether compositions, gelled alcohol compositions, gelled natural fats and oil compositions, and combinations thereof, to form a mixture; Stirring the mixture until the mixture is homogeneous; Cooling the mixture to form a two-phase gel composition having a viscosity greater than or equal to the viscosity of the gelled composition and having a viscosity greater than or equal to the viscosity of the solvent.
[42" claim-type="Currently amended] Heating the hydrophobic nonpolar solvent; Separately heating the gelled composition selected from the group consisting of gelled ester compositions, gelled ether compositions, gelled alcohol compositions, gelled natural fat and oil compositions, and combinations thereof; The heated solvent is mixed with the heated gelled composition to form a mixture; Stirring the mixture until the mixture is homogeneous; Cooling the mixture to form a two-phase gel composition having a viscosity greater than or equal to the viscosity of the gelled composition and having a viscosity greater than or equal to the viscosity of the solvent.
[43" claim-type="Currently amended] A gelled composition selected from the group consisting of a gelled ester composition, a gelled ether composition, a gelled alcohol composition, a gelled natural fat and oil composition, and combinations thereof, is mixed with a hydrophobic nonpolar solvent to provide a viscosity greater than the viscosity of the gelled composition. Forming a two-phase gel composition having a viscosity equal to or greater than the viscosity of the solvent and increasing the viscosity of the gelled composition.
[44" claim-type="Currently amended] 44. The method of claim 43, wherein the viscosity of the two-phase gel composition is substantially greater than or equal to the viscosity of the gelled composition and substantially greater than or equal to the viscosity of the solvent.
[45" claim-type="Currently amended] 44. The method of claim 43, wherein the viscosity of the two-phase gel composition is substantially greater than or equal to the sum of the viscosity of the gelled composition and the solvent.
[46" claim-type="Currently amended] 44. The method of claim 43, wherein the gelled ester composition contains a mixture of ester compounds and polymeric compounds selected from the group consisting of triblock copolymers, shaped polymers, radial polymers, multiblock copolymers, and combinations thereof.
[47" claim-type="Currently amended] 44. The gelled ether composition of claim 43, wherein the gelled ether composition contains a mixture of ether compounds and polymeric compounds selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers, and combinations thereof. Way.
[48" claim-type="Currently amended] 44. The gelled alcohol composition of claim 43, wherein the gelled alcohol composition contains a mixture of an alcohol compound and a polymer compound selected from the group consisting of diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers, and combinations thereof. Way.
[49" claim-type="Currently amended] 44. The polymer of claim 43 wherein the gelled natural fat and oil composition is selected from the group consisting of natural fat and oil compounds and diblock copolymers, triblock copolymers, shaped polymers, radial polymers, multiblock copolymers, and combinations thereof. A method containing a mixture of compounds.

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引用文献:

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公开号 | 申请日 | 公开日 | 申请人 | 专利标题

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法律状态:
2001-05-11|Priority to US09/853,552

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2001-05-11|Priority to US09/853,552

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2002-04-25|Application filed by 펜레코

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2002-11-20|Publication of KR20020086829A

优先权:

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申请号 | 申请日 | 专利标题

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US09/853,552|US6881776B2|1998-10-29|2001-05-11|Gel compositions|

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US09/853,552|2001-05-11|